Hydrogen-bond networks of 1,3-imidazolidine-2-thione: synthesis and structures of complexes of silver(I), copper(I), cadmium(II) and zinc(II)

被引：8
|
作者：
Zhu, Qinlei [1 ]
Chu, Wei [1 ]
Huang, Rudan [1 ]
Zhang, Jing [1 ]
Xu, Yanqing [1 ]
机构：
[1] Beijing Inst Technol, Sch Sci, Dept Chem, Beijing 100081, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 21期
关键词：
1,3-Imidazolidine-2-thione; Hydrogen-bond networks; Structure;
D O I：
10.1080/00958970802051041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Solution reactions of silver(I), copper(I), cadmium(II) and zinc(II) salts with 1,3-imidazolidine-2-thione (imdt) under diverse conditions yielded four complexes: [Cd(SC3H6N2)(2)(Ac)(2)] (1), [Zn(SC3H6N2)(2)(Ac)(2)] (2), [Cu-2(SC3H6N2)(6)]SO4 (3) and [Ag-2(SC3H6N2)(6)]SO4 (4). Complexes 1 and 2 are 1D and 2D hydrogen-bond aggregations. Complexes 3 and 4 are isostructural 3D hydrogen-bond networks. The diverse coordination modes of imdt and different anions are the major factors for three distinct hydrogen-bond structures.
引用
收藏
页码：3390 / 3400
页数：11
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