Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes

被引：42
|
作者：
Cornet, Stephanie M. [2 ]
Haeller, L. Jonas L. [3 ]
Sarsfield, Mark J. [4 ]
Collison, David [5 ]
Helliwell, Madeleine [5 ]
May, Iain [1 ]
Kaltsoyannis, Nikolas [3 ]
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87544 USA
[2] Univ Manchester, Ctr Radiochem Res, Sch Chem, Manchester M13 9PL, Lancs, England
[3] UCL, Dept Chem, London WC 1H, England
[4] UK Natl Nucl Lab, Cent Lab, Seascale CA20 1PG, Cumbria, England
[5] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 08期
基金：
美国能源部; 英国工程与自然科学研究理事会;
关键词：
CATION-CATION INTERACTIONS; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURES; NEPTUNYL CHLORIDE; COORDINATION; DISPROPORTIONATION; ABSORPTION; REDUCTION; CHEMISTRY; BOND;
D O I：
10.1039/b818973k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of [(NpO2Cl2)-O-VI(thf)](n) offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex[{(NpO2Cl2)-O-VI}{(NpO2Cl)-O-V(thf)(3)}(2)] allows molecular neptunyl(V) 'cation-cation' interactions to be probed.
引用
收藏
页码：917 / 919
页数：3
相关论文
共 50 条
  • [21] KINETICS OF REACTIONS BETWEEN NEPTUNIUM IONS - THE NEPTUNIUM(IV)-NEPTUNIUM(VI) REACTION IN PERCHLORATE SOLUTION
    HINDMAN, JC
    SULLIVAN, JC
    COHEN, D
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (12) : 3278 - 3280
  • [22] Liquid–liquid extraction of neptunium(VI) and neptunium(V) from carbonate solutions by methyltrioctylammonium carbonate in toluene
    Alexander V. Boyarintsev
    Sergey A. Perevalov
    Sergey I. Stepanov
    Alexander M. Chekmarev
    Journal of Radioanalytical and Nuclear Chemistry, 2021, 327 : 385 - 393
  • [23] Neptunium(V) incorporation/sorption with uranium(VI) alteration products
    Friese, JI
    Douglas, M
    Buck, EC
    Clark, SB
    Hanson, BD
    SCIENTIFIC BASIS FOR NUCLEAR WASTE MANAGEMENT XXVIII, 2004, 824 : 127 - 132
  • [24] Quantum Chemistry Study of Uranium(VI), Neptunium(V), and Plutonium(IV,VI) Complexes with Preorganized Tetradentate Phenanthrolineamide Ligands
    Xiao, Cheng-Liang
    Wu, Qun-Yan
    Wang, Cong-Zhi
    Zhao, Yu-Liang
    Chai, Zhi-Fang
    Shi, Wei-Qun
    INORGANIC CHEMISTRY, 2014, 53 (20) : 10846 - 10853
  • [25] Neptunium(V) and Uranium(VI) Reactions at the Magnetite (111) Surface
    Bots, Pieter
    van Veelen, Arjen
    Mosselmans, J. Frederick W.
    Muryn, Christopher
    Wogelius, Roy A.
    Morris, Katherine
    GEOSCIENCES, 2019, 9 (02)
  • [26] Neptunium(V) and neptunium(VI) solubilities in synthetic brines of interest to the waste isolation pilot plant (WIPP)
    Novak, CF
    Nitsche, H
    Silber, HB
    Roberts, K
    Torretto, PC
    Prussin, T
    Becraft, K
    Carpenter, SA
    Hobart, DE
    AlMahamid, I
    RADIOCHIMICA ACTA, 1996, 74 : 31 - 36
  • [27] The formation of neptunium peroxo complexes upon reduction of neptunium(VI) by hydrogen peroxide in concentrated solutions of alkalis
    Shilov, VP
    Gogolev, AV
    Pikaev, AE
    MENDELEEV COMMUNICATIONS, 1998, (06) : 220 - 222
  • [28] Neptunium(V) partitioning to uranium(VI) oxide and peroxide solids
    Douglas, M
    Clark, SB
    Friese, JI
    Arey, BW
    Buck, EC
    Hanson, BD
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (11) : 4117 - 4124
  • [29] In situ hydrothermal reduction of neptunium(VI) as a route to Neptunium(IV) phosphonates
    Bray, Travis H.
    Nelson, Anna-Gay D.
    Jin, Geng Bang
    Haire, Richard G.
    Albrecht-Schmitt, Thomas E.
    INORGANIC CHEMISTRY, 2007, 46 (26) : 10959 - 10961
  • [30] KINETICS OF THE NEPTUNIUM(IV)-NEPTUNIUM(VI) REACTION AND OF THE OXIDATION OF NEPTUNIUM(V) BY NITRIC-ACID IN TRIBUTYLPHOSPHATE-N DODECANE SOLUTIONS
    WEHREY, F
    GUILLAUME, B
    RADIOCHIMICA ACTA, 1989, 46 (02) : 95 - 100
12345