Neptunium(VI) chain and neptunium(VI/V) mixed valence cluster complexes

被引：42
|
作者：
Cornet, Stephanie M. [2 ]
Haeller, L. Jonas L. [3 ]
Sarsfield, Mark J. [4 ]
Collison, David [5 ]
Helliwell, Madeleine [5 ]
May, Iain [1 ]
Kaltsoyannis, Nikolas [3 ]
机构：
[1] Los Alamos Natl Lab, Los Alamos, NM 87544 USA
[2] Univ Manchester, Ctr Radiochem Res, Sch Chem, Manchester M13 9PL, Lancs, England
[3] UCL, Dept Chem, London WC 1H, England
[4] UK Natl Nucl Lab, Cent Lab, Seascale CA20 1PG, Cumbria, England
[5] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 08期
基金：
美国能源部; 英国工程与自然科学研究理事会;
关键词：
CATION-CATION INTERACTIONS; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURES; NEPTUNYL CHLORIDE; COORDINATION; DISPROPORTIONATION; ABSORPTION; REDUCTION; CHEMISTRY; BOND;
D O I：
10.1039/b818973k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of [(NpO2Cl2)-O-VI(thf)](n) offers the potential for more detailed exploration of neptunyl(VI) chemistry, while the synthesis of the mixed valence cluster complex[{(NpO2Cl2)-O-VI}{(NpO2Cl)-O-V(thf)(3)}(2)] allows molecular neptunyl(V) 'cation-cation' interactions to be probed.
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页码：917 / 919
页数：3
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