Combustion synthesis of ceramic matrices for immobilization of 14C

被引:4
|
作者
Bosc-Rouessac, F. [1 ]
Marin-Ayral, R. M. [1 ]
Haidoux, A. [1 ]
Massoni, N. [2 ]
Bart, F. [2 ]
机构
[1] Univ Montpellier 2, Inst Charles Gerhardt, UMR 5253, F-34095 Montpellier 5, France
[2] CEA Marcoule, Nucl Energy Div, DTCD SECM LM2C, F-30200 Bagnols Sur Ceze, France
关键词
Combustion synthesis; Radionuclide; Ceramic matrix; Carbides;
D O I
10.1016/j.jallcom.2007.11.098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study. the use of combustion synthesis for immobilization of C-14 was considered. Ceramic matrices have been prepared by this method using two different devices: one non-conventional with preheating of the samples and the other conventional device where ignition was produced thanks to tungsten filament. These two devices gave rise to different mechanisms of reactions involving different amounts of unreacted carbon graphite inside the matrix. The SHS samples were characterized by using scanning electron microscopy (SEM) and X-ray diffraction (XRD). (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:551 / 557
页数:7
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