Efficient Esterification of Fatty Acids with Alcohols Catalyzed by Zr(SO4)2 • 4H2O Under Solvent-Free Condition

被引：19

作者：

Juan, Joon Ching ^{[1
,2
,3
]}

Zhang, Jingchang ^{[3
]}

Yarmo, Mohd Ambar ^{[2
]}

机构：

[1] Monash Univ, Sch Sci, Selangor 46150, Malaysia

[2] Univ Kebangsaan Malaysia, Fac Sci & Technol, Sch Chem Sci & Food Technol, Adv Catalysis Technol Lab, Bangi 43600, Malaysia

[3] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Inst Modern Catalysis, Beijing 100029, Peoples R China

来源：

CATALYSIS LETTERS | 2008年 / 126卷 / 3-4期

基金：

中国国家自然科学基金;

关键词：

Zirconium sulfate; Esterification; Acid catalyst; Green chemistry;

D O I：

10.1007/s10562-008-9622-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zirconium sulfate (Zr(SO4)(2) center dot 4H(2)O) was an efficient catalyst for the esterification of fatty acids and alcohols under solvent-free condition. The esterification of fatty acid with branched alcohols using Zr(SO4)(2) center dot 4H(2)O catalyst gave a good yield of the corresponding ester. The zirconium sulfate Bronsted acid site was suggested to be the catalytically active species in this reaction. In addition, Zr(SO4)(2) center dot 4H(2)O compound is a potential green catalyst due to its high catalytic activity and low toxicity. This compound is also cost effective, easy to handle, is easily recovered by simple filtration and can be recycled for further reactions.

引用

页码：319 / 324

页数：6

共 50 条

[31] PHASE TRANSITION AND STRUCTURE OF K2Fe(SO4)•4H2O
Ishigami, H.
Sumita, M.
Tsunashima, Y.
Sato, S.
Shiro, M.
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2002, 58 : C147 - C147
[32] Fe2(SO4)3•xH2O catalytic esterification of aliphatic carboxylic acids with alcohols
Zhang, GS
SYNTHETIC COMMUNICATIONS, 1998, 28 (07) : 1159 - 1162
[33] Hydrogen bonding in goldichite, KFe(SO4)2⋅4H2O: structure refinement
Zhuming Yang
Gerald Giester
Mineralogy and Petrology, 2018, 112 : 135 - 142
[34] Fe2(SO4)2 QQ xH2O Catalytic Esterification of Aliphatic Carboxylic Acids with Alcohols
Synth Commun, 7 (1159):
[35] DIMERIC SULPHATE HYDRATES OF ZIRCONIUM - ZR(SO4)2,7H2O AND ALPHA-ZR(SO4)2,5H2O
BEAR, IJ
MUMME, WG
CHEMICAL COMMUNICATIONS, 1968, (11) : 609 - &
[36] TiO2:: A simple and an efficient catalyst for esterification of phenols under solvent-free condition
Pasha, Mohamed Afzal
Manjula, Krishnappa
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2008, 47 (04): : 597 - 600
[37] Contributions to the stereochemistry of zirconium oxysalts—part IV: syntheses and crystal structures of Zr2(OH)2(XO4)3·4H2O (X = S, Se), Zr(SO4)2·4H2O, and Zr(SeO3)2
Manfred Wildner
Christian L. Lengauer
Herta Effenberger
Gerald Giester
Monatshefte für Chemie - Chemical Monthly, 2022, 153 : 139 - 151
[38] Ce(SO4)2•4H2O Mediated Synthesis of Flavones and 2-Phenyl-4-quinolones
Liu, Ruihuan
Wang, Xuli
Cheng, Fei
Li, Fushuang
Xu, Kangping
Tan, Guishan
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2016, 36 (11) : 2677 - 2682
[39] Physicochemical Analysis of the System Zr(SO4)2-Na2SO4-H2SO4-H2O at 25°C
Shulyak, D. V.
Skiba, G. S.
Kuznetsov, V. Ya.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 61 (06) : 776 - 780
[40] Phase Formation in the Zr(SO4)2-H2SO4-KF-KCl-H2O System
Godneva, M. M.
Motov, D. L.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 1999, 44 (10) : 1653 - 1656

← 1 2 3 4 5 →