Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO2/γ-Al2O3Catalyst

被引：1
|
作者：
Badmaev, Sukhe [1 ,2 ]
Sobyanin, Vladimir [1 ]
机构：
[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Dept Nat Sci, Pirogova St 2, Novosibirsk 630090, Russia
来源：
ENERGIES | 2020年 / 13卷 / 14期
关键词：
dimethoxymethane; hydrogen production; CuO-CeO2; gamma-Al2O3; oxidative steam reforming; partial oxidation; copper catalyst; fuel cell; FUEL-CELLS; SELECTIVE PRODUCTION; CUZNAL CATALYSTS; DIMETHYL ETHER; METHANOL; PERFORMANCE; FEEDSTOCKS; STATE; H-2;
D O I：
10.3390/en13143684
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The catalytic properties of CuO-CeO(2)supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/gamma-Al(2)O(3)catalyst provided complete DMM conversion and hydrogen productivity > 10 L h(-1)g(cat)(-1)at 280 degrees C, GHSV (gas hourly space velocity) = 15,000 h(-1)and DMM:O-2:H2O:N-2= 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.
引用
收藏
页数：10
相关论文
共 50 条
  • [21] Hydrogen production via methanol steam reforming over Au/CuO, Au/CeO2, and Au/CuO-CeO2 catalysts prepared by deposition-precipitation
    Pongstabodee, Sangobtip
    Monyanon, Sutarawadee
    Luengnaruemitchai, Apanee
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (04) : 1272 - 1279
  • [22] CeO2 promoted CuO/Al2O3 catalysts for hydrogen production from methanol steam reforming
    Zhang, XR
    Shi, PF
    Zhao, JX
    Zhao, MY
    Liu, CT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U18 - U18
  • [23] Catalytic performance of manganese doped CuO-CeO2 catalysts for selective oxidation of CO in hydrogen-rich gas
    Guo, Xiaolin
    Li, Jing
    Zhou, Renxian
    FUEL, 2016, 163 : 56 - 64
  • [24] Hydrogen production by ethanol steam reforming over a commercial Pd/-γ-Al2O3 catalyst
    Goula, MA
    Kontou, SK
    Tsiakaras, PE
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 49 (02) : 135 - 144
  • [25] Oxidative steam reforming of methanol over CuO/ZnO/CeO2/ZrO2/Al2O3 catalysts
    Chang, Cheng-Chun
    Chang, Ching-Tu
    Chiang, Shu-Jen
    Liaw, Biing-Jye
    Chen, Yin-Zu
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (15) : 7675 - 7683
  • [26] Experimental study of hydrogen production via the steam reforming of hydrogen-rich biomass pyrolysis gas under the catalysis of Ni/γ-Al2O3
    Wang T.-P.
    Hu S.-H.
    Liu J.
    Hu B.
    Sun H.-D.
    Zhang Z.-X.
    Lu Q.
    Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2023, 51 (11): : 1691 - 1700
  • [27] Steam Conversion of Dimethyl Ether into a Hydrogen-Bearing Gas on Bifunctional CuO-CeO2/gamma-Al2O3 Catalysts
    Badmaev, S. D.
    Sobyanin, V. A.
    CHEMISTRY FOR SUSTAINABLE DEVELOPMENT, 2007, 15 (01): : 117 - 121
  • [28] H2-rich synthesis gas production over Co/Al2O3 catalyst via glycerol steam reforming
    Cheng, Chin Kui
    Foo, Say Yei
    Adesina, Adesoji A.
    CATALYSIS COMMUNICATIONS, 2010, 12 (04) : 292 - 298
  • [29] Steam reforming and oxidative steam reforming of ethanol over PtKCo/CeO2 catalyst
    Greluk, Magdalena
    Slowik, Grzegorz
    Rotko, Marek
    Machocki, Andrzej
    FUEL, 2016, 183 : 518 - 530
  • [30] Selective CO oxidation in hydrogen-rich gas over CuO/CeO2 catalysts
    Zou, Hanbo
    Dong, Xinfa
    Lin, Weiming
    APPLIED SURFACE SCIENCE, 2006, 253 (05) : 2893 - 2898
12345