cyclodextrin-based micropores;
large mesopores;
organosilica;
self-assembly;
templates;
D O I:
10.1002/marc.200300282
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
A novel mesoporous organosilica with additional cyclodextrin-based micropores has been synthesized from tetraethoxysilane (TEOS) and cyclodextrin-based silane monomer precursors and triblock PEO-PPO-PEO (poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide)) copolymer P123 as the structure-directing template with the aid of sodium chloride and the supramolecular assembly of cyclodextrins with P123.
机构:
Nankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R ChinaNankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
Tian, Jun
Chen, Yong
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机构:
Nankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R ChinaNankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
Chen, Yong
Li, Wei
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机构:
Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Coll Chem, Tianjin 300071, Peoples R ChinaNankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
Li, Wei
Liu, Yu-Ping
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机构:
Nankai Univ, Res Ctr Analyt Sci, Tianjin 300071, Peoples R ChinaNankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
Liu, Yu-Ping
Zhou, Wei-Lei
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机构:
Nankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R ChinaNankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
Zhou, Wei-Lei
Liu, Yu
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机构:
Nankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
Nankai Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R ChinaNankai Univ, State Key Lab Elementoorgan Chem, Coll Chem, Tianjin 300071, Peoples R China
机构:
Al Ain Univ, Coll Pharm, Abu Dhabi Campus,POB 112612, Abu Dhabi, U Arab Emirates
Al Ain Univ, AAU Hlth & Biomed Res Ctr HBRC, POB 112612, Abu Dhabi, U Arab EmiratesUVAS, Inst Pharmaceut Sci, Lahore 54000, Pakistan