Hydrothermal syntheses, crystal structures and characterization of new vanadoborates: The novel decorated cage cluster [V6B22O44(OH)10]

被引：27

作者：

Liu, Xing ^{[1
]}

Zhou, Jian ^{[1
,2
]}

An, Litao ^{[3
]}

Chen, Rong ^{[1
]}

Hu, Feilong ^{[2
]}

Tang, Qiuling ^{[2
]}

机构：

[1] Chongqing Normal Univ, Coll Chem, Chongqing 401331, Peoples R China

[2] Yulin Normal Univ, Coll Chem & Mat, Yulin 537000, Peoples R China

[3] Huaiyin Normal Univ, Coll Chem & Chem Engn, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2013年 / 201卷

关键词：

Hydrothermal syntheses; Vanadates; Borates; Structure; Spectroscopic properties; MOLYBDENUM-VANADIUM POLYOXOMETALATE; TRANSITION-METAL-COMPLEX; POLYOXOVANADIUM BORATE; SOLVOTHERMAL SYNTHESIS; CHAIN; POLYMER; NETWORK; BRIDGES; SYSTEM;

D O I：

10.1016/j.jssc.2013.02.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new vanadoborates [H(3)teta](3)[V12B18O54(OH)(6)(H2O)]center dot(H3O)center dot 5H(2)O (1, teta=triethylenetetramine), [H(4)teta](2)[V6B22O44(OH)(10)]center dot 4.5H(2)O (2) and [H(4)tepa](2)[V6B22O44(OH)(10)]center dot 4H(2)O (3, tepa=tetraethylenepentamine) have been hydrothermally synthesized and structurally characterized. 1 contains cage cluster [V12B18O54(OH)(6)(H2O)](10-) based on one puckered B18O36(OH)(6) ring sandwiched between two V6O15 clusters. Both 2 and 3 contain new decorated cage cluster [V6B22O44(OH)(10)](8-) built up from a central band of [V6O18] capped top and bottom by two raft-like polyborate [B11O20(OH)(4)] units. The magnetic susceptibility of 3 demonstrates the presence of antiferromagnetic interaction between V-IV cations. The theoretical band structure and spectroscopic properties have been also studied. (C) 2013 Elsevier Inc. All rights reserved.

引用

页码：79 / 84

页数：6