Hydrothermal Synthesis, Crystal Structure and Photoluminescent Property of Nd(III) Complex Constructed from 5-(Isonicotinamido)-isophthalic Acid

被引：1

作者：

Chen Man-Sheng ^{[1
]}

Xu Jin-Sheng ^{[1
]}

Deng Yi-Fang ^{[1
]}

Zhang Chun-Hua ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

Nie Xue ^{[1
]}

机构：

[1] Hengyang Normal Univ, Coll Hunan Prov, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 12期

关键词：

5-(isonicotinamido)isophthalic acid; crystal structure; hydrothermal synthesis; photoluminescence; SUPRAMOLECULAR ISOMERISM; ORGANIC FRAMEWORKS;

D O I：

10.3969/j.issn.1001-4861.2013.00.390

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Nd(HINAIP)(INAIP)(H2O)(2)](n)center dot nH(2)O was obtained by hydrothermal assembly of Nd(III) salt with a 5-(isonicotinamido)isophthalic acid (H(2)INAIP) and its crystal structure was determined by X-ray single-crystal diffraction. It is of triclinic, P (1) over bar space group. Single-crystal X-ray diffraction analysis revealed that the HINAIP(-) and INAIP(2-) ligands connect Nd(III)-carboxylate chains to form 2D layers in complex 1. Finally, It was extended to 3D supramolecular structures by H-bonding interactions. The complex was characterized by TG, IR. UV and near IR fluorescence spectra. CCDC: 958122.

引用

页码：2673 / 2677

页数：5

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