Three-dimensional fourfold interpenetrated (10,3)-b nickel(II) framework with 5-(isonicotinamido)isophthalate

被引:28
|
作者
Chen, Man-Sheng [1 ]
Bai, Zheng-Shuai
Su, Zhi
Chen, Shui-Sheng
Sun, Wei-Yin
机构
[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn,State Key Lab Coord, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Hengyang Normal Univ, Dept Chem & Met Sci, Hengyang 421008, Peoples R China
基金
中国国家自然科学基金;
关键词
Nickel(II) complex; metal-organic framework; Hydrothermal reaction; (10,3)-b Net; Fourfold Interpenetration; METAL-ORGANIC FRAMEWORKS; SINGLE-MOLECULE MAGNETS; BUILDING UNITS; NETWORKS; POLYMERS; DESIGN; FUNCTIONALITY; ARCHITECTURES; CHEMISTRY; SORPTION;
D O I
10.1016/j.inoche.2009.04.015
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new three-dimensional nickel(II) metal-organic framework [Ni(INAIP)(H2O)2]n.nH2O (1) [H2INAIP = 5-(isonicotinamido)isophthalic acid] was synthesized under hydrothermal conditions, and characterized by single-crystal X-ray structure determination, thermogravimetric analysis, X-ray powder diffraction, IR and magnetic studies. The compound 1 has (10, 3)-b topology with not well known fourfold interpenetration, in which both Ni(II) atoms and INAIP2- ligands act as three-connected nodes.
引用
收藏
页码:530 / 533
页数:4
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