Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction

被引：10

作者：

Trofimov, Boris A. ^{[1
]}

Vasilevsky, Sergei F. ^{[2
]}

Gusarova, Nina K. ^{[1
]}

Malysheva, Svetlana R. ^{[1
]}

Baranov, Denis S. ^{[2
]}

Mamatyuk, Victor I. ^{[3
]}

Gatilov, Yurii V. ^{[3
]}

机构：

[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia

[2] Russian Acad Sci, Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia

[3] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2008年 / 18卷 / 06期

关键词：

D O I：

10.1016/j.mencom.2008.11.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [(Z-PhCH=CH)(3)P](2)PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 degrees C, 15 min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P](2)PdCl2, the most common catalyst for this type of reactions.

引用

页码：318 / 319

页数：2

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