An amperometric solid state NO sensor using a LaGaO3 electrolyte for monitoring exhaust gas

被引:8
|
作者
Dutta, Atanu [1 ]
Ishihara, Tatsumi [1 ]
机构
[1] Kyushu Univ, Fac Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
关键词
amperometric sensor; current response; exhaust gas monitoring; high temperature sensor; LaGaO3; LSM electrode; mixed potential; Ni doping to LaGaO3; NO oxidation electrode; NO sensor; oxygen reduction electrode; pollution; selectivity; sensitivity; solid electrolyte;
D O I
10.1080/10426910500464404
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A LaGaO3-based electrochemical sensor in the amperometric mode was demonstrated as highly sensitive to NO in the temperature range 500-700 degrees C. Sensor performance was found dependent on the Ni doping of LaGaO3. Using optimized electrode materials, highest sensitivity was achieved as high as 2409 mu A/decade (at 550 degrees C) when Ni doping to electrolyte was 7 mol%. The selectivity of the sensor was found very high to NO with respect to the typical coexisting gases in the exhaust environment. The sensing principle was observed to follow the mixed potential behavior.
引用
收藏
页码:225 / 228
页数:4
相关论文
共 50 条
  • [1] Amperometric solid-state gas sensor using LaGaO3 based perovskite oxide electrolyte for detecting hydrocarbon in exhaust gas -: II.: Improvement of inactive electrode performance
    Dutta, A
    Ishihara, T
    Nishiguchi, H
    Takita, Y
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (05) : H122 - H127
  • [2] Amperometric NOX sensor based on oxygen pumping current by using LaGaO3-based solid electrolyte for monitoring exhaust gas
    Dutta, A
    Ishihara, T
    SENSORS AND ACTUATORS B-CHEMICAL, 2005, 108 (1-2) : 309 - 313
  • [3] Solid state amperometric hydrocarbon sensor for monitoring exhaust gas using oxygen pumping current
    Ishihara, T
    Fukuyama, M
    Dutta, A
    Kabemura, K
    Nishiguchi, H
    Takita, Y
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (10) : H241 - H245
  • [4] Solid-state amperometric CH4 sensor using, LaGaO3-based electrolyte
    Bi, Zhonghe
    Matsumoto, Hiroshige
    Ishihara, Tatsumi
    SOLID STATE IONICS, 2008, 179 (27-32) : 1641 - 1644
  • [5] Amperometric hydrocarbon sensor using La(Sr)Ga(Fe)O3 solid electrolyte for monitoring in exhaust gas
    Dutta, A
    Nishiguchi, H
    Takita, Y
    Ishihara, T
    SENSORS AND ACTUATORS B-CHEMICAL, 2005, 108 (1-2): : 368 - 373
  • [6] An amperometric solid-state gas sensor using a LaGaO3-based perovskite oxide electrolyte for detecting hydrocarbon in exhaust gas.: A bimetallic anode for improving sensitivity at low temperature
    Dutta, A
    Ishihara, T
    Nishiguchi, H
    CHEMISTRY OF MATERIALS, 2004, 16 (24) : 5198 - 5204
  • [7] Intermediate temperature solid oxide electrolysis cell using LaGaO3 based perovskite electrolyte
    Ishihara, Tatsumi
    Jirathiwathanakul, Nitiphong
    Zhong, Hao
    ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (05) : 665 - 672
  • [8] Intermediate temperature solid oxide fuel cell using Ni doped LaGaO3 electrolyte
    Ishihara, T
    Shibayama, T
    Arikawa, H
    Honda, H
    Nishiguchi, H
    Takita, Y
    SOLID OXIDE FUEL CELLS (SOFC VI), 1999, 99 (19): : 869 - 878
  • [9] Measurement of Gibbs energy of formation of LaGaO3 using a composition-graded solid electrolyte
    K. Thomas Jacob
    Niladri Dasgupta
    Helfried Näfe
    Fritz Aldinger
    Journal of Materials Research, 2000, 15 : 2836 - 2843
  • [10] Measurement of Gibbs energy of formation of LaGaO3 using a composition-graded solid electrolyte
    Jacob, KT
    Dasgupta, N
    Näfe, H
    Aldinger, F
    JOURNAL OF MATERIALS RESEARCH, 2000, 15 (12) : 2836 - 2843