Interacting Superparamagnetic Iron(II) Oxide Nanoparticles: Synthesis and Characterization in Ionic Liquids

被引：10
|
作者：
Leal, Barbara C. [1 ]
Scholten, Jackson D. [1 ]
Alves, Maria C. M. [1 ]
Morais, Jonder [1 ,2 ]
de Pedro, I. [1 ,3 ]
Fernandez Barquin, L. [1 ,3 ]
Dupont, Jairton [1 ,4 ]
机构：
[1] Univ Fed Rio Grande do Sul, Inst Chem, Ave Bento Goncalves 9500, BR-91501970 Porto Alegre, RS, Brazil
[2] Univ Fed Rio Grande do Sul, Inst Phys, Ave Bento Goncalves 9500, BR-91501970 Porto Alegre, RS, Brazil
[3] Univ Cantabria, Fac Ciencias, E-39005 Santander, Spain
[4] Univ Nottingham, Sch Chem, Univ Pk, Nottingham NG7 2RD, England
来源：
INORGANIC CHEMISTRY | 2016年 / 55卷 / 02期
关键词：
MAGNETIC-PROPERTIES; CATALYSIS; HYDROGENATION;
D O I：
10.1021/acs.inorgchem.5b02320
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Interacting superparamagnetic iron(II) oxide nanoparticles (NPs) with sizes of 5.3 1.6 nm were prepared by simple decomposition of [Fe(COT)(2)] (COT = 1,3,5,7-cyclooctatetraene) with 5 bar of H-2 in 1-n-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (BMINTf2) ionic liquid (IL). The static and dynamic magnetic characterization revealed a superparamagnetic behavior with weak dipolar interactions of these NPs. In situ structural studies by X-ray absorption spectroscopy demonstrated that they consist of nanostructured FeO. This approach is an appropriate method to prepare and stabilize nanostructured FeO particles, where the presence of an IL proved to be fundamental to suppress the aggregation and usual overoxidation of the FeO NPs.
引用
收藏
页码：865 / 870
页数：6
相关论文
共 50 条
  • [41] Characterization of Superparamagnetic Iron Oxide Nanoparticles and Its Application in Protein Purification
    Okoli, Chuka
    Fornara, Andrea
    Qin, Jian
    Toprak, Muhammet S.
    Dalhammar, Gunnel
    Muhammed, Mamoun
    Rajarao, Gunaratna K.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2011, 11 (11) : 10201 - 10206
  • [42] Controlled synthesis of superparamagnetic iron-oxide nanoparticles by phase transformation
    Laurenzi, Mark A., III
    Carpenter, Everett E.
    JOURNAL OF APPLIED PHYSICS, 2012, 111 (07)
  • [43] Sophorolipid-coated superparamagnetic iron oxide nanoparticles: Synthesis and structure
    Lassenberger, Andrea
    Reimhult, Erik
    Baccile, Niki
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [44] Size-controlled synthesis of monodisperse superparamagnetic iron oxide nanoparticles
    Zhu, Yuan
    Jiang, F. Y.
    Chen, Kexin
    Kang, Feiyu
    Tang, Z. K.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (34) : 8549 - 8553
  • [45] A Novel Approach for the Synthesis of PEGylated Monodispersed Superparamagnetic Iron Oxide Nanoparticles
    Tserotas, P.
    Statharas, E.
    Kartswnakis, I.
    MATERIALS AND APPLICATIONS FOR SENSORS AND TRANSDUCERS III, 2014, 605 : 693 - 696
  • [46] Synthesis and magnetostructural studies of amine functionalized superparamagnetic iron oxide nanoparticles
    Salunkhe, A. B.
    Khot, V. M.
    Ruso, J. M.
    Patil, S. I.
    RSC ADVANCES, 2015, 5 (24): : 18420 - 18428
  • [47] Synthesis, characterization, and in vitro biological evaluation of highly stable diversely functionalized superparamagnetic iron oxide nanoparticles
    Dipsikha Bhattacharya
    Sumanta K. Sahu
    Indranil Banerjee
    Manasmita Das
    Debashish Mishra
    Tapas K. Maiti
    Panchanan Pramanik
    Journal of Nanoparticle Research, 2011, 13
  • [48] Synthesis, characterization and theranostic evaluation of Indium-111 labeled multifunctional superparamagnetic iron oxide nanoparticles
    Zolata, Hamidreza
    Davani, Fereydoun Abbasi
    Afarideh, Hossein
    NUCLEAR MEDICINE AND BIOLOGY, 2015, 42 (02) : 164 - 170
  • [49] Size and Shape Controlled Synthesis and Characterization of Superparamagnetic Iron Oxide Nanoparticles by Co-Precipitation Method
    Seyed, Sadjadi Mirabdullah
    Ebrahim, Babaei Seyed
    RESEARCH JOURNAL OF CHEMISTRY AND ENVIRONMENT, 2013, 17 (12): : 60 - 64
  • [50] Synthesis, characterization, and in vitro biological evaluation of highly stable diversely functionalized superparamagnetic iron oxide nanoparticles
    Bhattacharya, Dipsikha
    Sahu, Sumanta K.
    Banerjee, Indranil
    Das, Manasmita
    Mishra, Debashish
    Maiti, Tapas K.
    Pramanik, Panchanan
    JOURNAL OF NANOPARTICLE RESEARCH, 2011, 13 (09) : 4173 - 4188
12345