Intrinsic chemistry of [OUCH]+: reactions with H2O, CH3CN and O2

被引：9
|
作者：
Metzler, Luke J. [1 ]
Farmen, Christopher T. [1 ]
Corcovilos, Theodore A. [2 ]
Van Stipdonk, Michael J. [1 ]
机构：
[1] Duquesne Univ, Dept Chem & Biochem, 600 Forbes Ave, Pittsburgh, PA 15282 USA
[2] Duquesne Univ, Dept Phys, 600 Forbes Ave, Pittsburgh, PA 15282 USA
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2021年 / 23卷 / 08期
关键词：
D O I：
10.1039/d1cp00177a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report the first experimental study of the intrinsic chemistry of a U-methylidyne species, focusing on reaction of [OUCH](+) with H2O, O-2 and CH3C N in the gas phase. DFT was also used to determine reaction pathways, and establish the mechanism by which [OUCH](+) is formed through collision-induced dissociation of [UO2(C CH)](+).
引用
收藏
页码：4475 / 4479
页数：5
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