The crystal structure of a distannoxane containing 4-carboxybenzo-15-crown-5 ligands

被引：0
|
作者：
Kemmer, M
Gielen, M
Willem, R
Tiekink, ERT
机构：
[1] Free Univ Brussels, Fac Sci, B-1050 Brussels, Belgium
[2] Univ Adelaide, Fac Sci Appl, Dept Gen & Organ Chem, Adelaide, SA 5005, Australia
[3] Univ Adelaide, High Resolut NMR Ctr, Adelaide, SA 5005, Australia
[4] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia
来源：
MAIN GROUP METAL CHEMISTRY | 2000年 / 23卷 / 05期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The X-ray crystal structure of {[nBu(2)Sn(O2CR)](2)O}(2), where R is 4-benzo-15-crown-5, shows the molecule to be centrosymmetric and comprises a central Sn2O2 core to which are linked to two exocyclic tin atoms. Almost symmetric carboxylate bridges provide additional links between pairs of endo- and exo-cyclic tin atoms and the remaining carboxylate ligands are monodentate, coordinating the exocyclic tins exclusively. The coordination geometries are distorted trigonal bipyramidal.
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页码：271 / 275
页数：5
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