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Total synthesis, structural revision, and absolute configuration of (+)-clavosolide A
被引:43
|作者:
Son, JB
[1
]
Kim, SN
[1
]
Kim, NY
[1
]
Lee, DH
[1
]
机构:
[1] Sogang Univ, Dept Chem, Seoul 121742, South Korea
关键词:
D O I:
10.1021/ol052851n
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
Enantioselective synthesis of 3, a revised structure for clavosolide A, was completed. Both H-1 and C-13 NMR spectra of the natural and synthetic compounds were identical, and optical rotation measurements identified the absolute configuration of the natural clavosolide A as the enantiomer of 3.
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页码:661 / 664
页数:4
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