Total synthesis, structural revision, and absolute configuration of (+)-clavosolide A

被引：43

作者：

Son, JB ^{[1
]}

Kim, SN ^{[1
]}

Kim, NY ^{[1
]}

Lee, DH ^{[1
]}

机构：

[1] Sogang Univ, Dept Chem, Seoul 121742, South Korea

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 04期

关键词：

D O I：

10.1021/ol052851n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselective synthesis of 3, a revised structure for clavosolide A, was completed. Both H-1 and C-13 NMR spectra of the natural and synthetic compounds were identical, and optical rotation measurements identified the absolute configuration of the natural clavosolide A as the enantiomer of 3.

引用

页码：661 / 664

页数：4

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