Stereoselective interaction between DNA and chiral surfaces

被引:74
|
作者
Tang, Kangjian [1 ,3 ]
Gan, Hui [1 ]
Li, Yong [1 ]
Chi, Lifeng [1 ,2 ]
Sun, Taolei [1 ,2 ]
Fuchs, Harald [1 ,2 ]
机构
[1] Univ Munster, Inst Phys, D-48149 Munster, Germany
[2] Univ Munster, Ctr Nanotechnol, D-48151 Munster, Germany
[3] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
关键词
D O I
10.1021/ja8044184
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ssDNA exhibits much different adsorption behaviors on enantiomer modified surfaces, which can be explained by the stereoselective H-bond interaction between DNA and the chiral surfaces. This effect not only may help to understand the stereospecific cell/substrate interaction and the origin of the chiral preference in nature but also brings novel insights to the study of DNA properties and the application in biochemical devices.
引用
收藏
页码:11284 / +
页数:3
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