Di-μ-chloro-bis[chloro(tricyclohexylphosphine-κP)mercury(II)]

被引：7
|
作者：
Liu, LH
Zhang, QF [1 ]
Leung, WH
机构：
[1] Anhui Univ Technol, Dept Chem & Chem Engn, Maanshan 243002, Anhui, Peoples R China
[2] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804005288
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Hg2Cl4(C18H33P)(2)], there are two independent centrosymmetric Hg-II dimers, the asymmetric unit containing half of each. The coordination about each Hg atom is highly distorted tetrahedral, three sites being occupied by one terminal and two bridging Cl atoms, and the remaining site by the P atom of a tricyclohexylphosphine ligand (PCy3). The Hg atoms in the dimers are 3.792 (3) and 3.940 (3) Angstrom. apart and are thus non-bonded.
引用
收藏
页码：M394 / M395
页数：2
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