Stimuli-Responsive Polypeptide Materials Prepared by Ring-Opening Polymerization of α-Amino Acid N-Carboxyanhydrides

被引：51
|
作者：
Zhang, Shusheng [1 ,2 ]
Li, Zhibo [1 ,2 ]
机构：
[1] Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
来源：
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS | 2013年 / 51卷 / 07期
基金：
中国国家自然科学基金;
关键词：
biopolymers; NCA; polypeptides; ring-opening polymerization; structure-property relations; THERMAL RESPONSE; MOLECULAR-WEIGHT; HYBRID MICELLES; DRUG; TEMPERATURE; POLYMERS; CHAIN; GLYCOPOLYPEPTIDES; GLYCOL); HOMOPOLYMER;
D O I：
10.1002/polb.23263
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Design and synthesis of biodegradable stimuli-responsive polypeptides are important areas considering their promising applications in biomedical fields. This article summarizes the most recent progresses in the development of stimuli-responsive polypeptide materials prepared via ring-opening polymerization of alpha-amino acid N-carboxyanhydrides. We discuss the design, synthesis and structure-property correlation of emerging materials including thermo-responsive, redox-responsive, photo-responsive and biomolecule responsive polypeptides. Considering the unique structural features of amino acids, we try to emphasize that the thermo-responsive properties not only depend on the amino acid structure but also rely on the secondary structures of polypeptides. (C) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013, 51, 546-555
引用
收藏
页码：546 / 555
页数：10
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