1,4-asymmetric induction from chiral delta-oxygenated allylic tin reagents

被引：6
|
作者：
Nishigaichi, Y
Yoshikawa, M
Takigawa, Y
Takuwa, A
机构：
[1] Department of Chemistry, Faculty of Science, Shimane University, Matsue 690
来源：
CHEMISTRY LETTERS | 1996年 / 11期
关键词：
D O I：
10.1246/cl.1996.961
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new type of asymmetric induction from allylic tin reagents is developed. A chiral allylic tin which has an oxygen substituent (ether or eater) at its delta-position successfully induces a new chirality in a 1,4-induction mode in the reaction with aldehydes via the transmetallation with SnCl4.
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页码：961 / 962
页数：2
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