Synthesis and structure of a μ-oxo diiron(III) complex with an N-pyridylmethyl-N,N-bis(4-methylbenzimidazol-2-yl)amine ligand and its catalytic property for hydrocarbon oxidation

被引：6
|
作者：
Sun, Hongfei [1 ]
Wang, Mei [1 ]
Li, Fei [1 ]
Li, Ping [1 ]
Zhao, Zhenbo [1 ]
Sun, Licheng [1 ,2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, Dalian 116012, Peoples R China
[2] Royal Inst Technol KTH, Sch Chem Sci & Engn, Dept Chem, S-10044 Stockholm, Sweden
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2008年 / 22卷 / 10期
基金：
瑞典研究理事会;
关键词：
non-heme iron; diiron complex; alkane oxidation; epoxidation; imidazolyl ligand;
D O I：
10.1002/aoc.1444
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A mu-oxo diiron(III) complex [{Fe(pbba)Cl}(2)(mu-O)]Cl-2 (1, pbba = N-pyridylmethyl-N,N-bis(4-methylbenzimidazol-2-yl)amine) bearing multi-imidazolyl motifs was synthesized and characterized by X-ray crystallography to closely mimic the structural features of methane monooxygenase. As shown by its X-ray crystal structure, complex 1 is a centrosymmetric dimer with an Fe-O-Fe angle of 180 degrees, and pseudo-octahedral around each iron(III) center. The catalytic ability of title compound in the oxidation of alkane and alkene is investigated by employing tert-butylhydroperoxide and m-chloroperbenzoic acid as oxidants under mild conditions. The catalytic oxidation results showed that radical intermediate dominates the oxidation process. Copyright (C) 2008 John Wiley & Sons, Ltd.
引用
收藏
页码：573 / 576
页数：4
相关论文
共 50 条
  • [41] The synthesis and structure of a neutral tetranuclear zinc(II) complex [Zn4(L)4][LH2=N,N-bis(2-mercaptoethyl)benzylamine]
    Spencer, DJE
    Blake, AJ
    Parsons, S
    Schröder, M
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (07): : 1041 - 1042
  • [42] Synthesis, crystal structure, and thermodynamics of a high-nitrogen copper complex with N, N-bis-(1(2)H-tetrazol-5-yl) amine
    Xue B.-D.
    Yang Q.
    Chen S.-P.
    Gao S.-L.
    Journal of Thermal Analysis and Calorimetry, 2010, 101 (3) : 997 - 1002
  • [43] Structure of the cobalt(III) complex with a new hexadentate ligand, anion of N,N-bis(benzimidazol-2-ylmethyl)ethylenediamine-N',N'-diacetic acid, [Co(Bim(2)acida)]Cl.5H(2)O
    Polyakova, IN
    Sergienko, VS
    Poznyak, AL
    Burshtein, IF
    Kirakosyan, GA
    KOORDINATSIONNAYA KHIMIYA, 1997, 23 (02): : 112 - 116
  • [44] Synthesis, Crystal Structure and Magnetic Property of a Chain-like Dicyanamide Manganese(III) Complex with N,N′-Bis(2-salicylidene)propane-1,2-diamine Ligand
    Ren, S.
    Ma, S-L
    POLISH JOURNAL OF CHEMISTRY, 2009, 83 (07) : 1285 - 1291
  • [45] Synthesis, structure and redox properties of a new ruthenium(II) complex containing the flexible tridentate ligand N,N-bis(2-pyridylmethyl)ethylamine, cis-fac-Ru(bpea)22+, and its homologue attached covalently to a polypyrrole film
    Romero, I
    Rodríguez, M
    Llobet, A
    Collomb-Dunand-Sauthier, MN
    Deronzier, A
    Parella, T
    Stoeckli-Evans, H
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (11): : 1689 - 1694
  • [46] Synthesis,Structure and Norbornene Polymerization Activity of a Novel Palladium(Ⅱ) Complex with N,N-bis(2-benzoyl-3-oxobutane)-trans-1,2-diaminocyclohexane Ligand
    孟素芹
    李超
    俞颖华
    兰梅英
    陈建新
    张治纯
    Chinese Journal of Structural Chemistry, 2014, (01) : 115 - 121
  • [47] Synthesis,Structure and Norbornene Polymerization Activity of a Novel Palladium(Ⅱ) Complex with N,N-bis(2-benzoyl-3-oxobutane)-trans-1,2-diaminocyclohexane Ligand
    孟素芹
    李超
    俞颖华
    兰梅英
    陈建新
    张治纯
    结构化学, 2014, 33 (01) : 115 - 121
  • [48] Synthesis, crystal structure and catalytic property of a copper(II) complex derived from N,N′-Bis(4-methylsalicylidene)cyclohexane-1,2-diamine
    Qiu, Xiao-Yang
    INORGANIC AND NANO-METAL CHEMISTRY, 2018, 48 (06) : 263 - 266
  • [49] The Structure of a Cobalt(III) Complex with a New Hexadentate Ligand, Anion of N,N-Bis(benzimidazol-2-ylmethyl)ethylenediamine-N′,N′-Diacetic Acid, [Co(Bim2aeida]Cl • 5.5H2O
    Polyakova, I. N.
    Sergienko, V. S.
    Poznyak, A. L.
    Burshtein, I. F.
    Kirakosyan, G. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1997, 23 (02) : 101 - 105
  • [50] Synthesis, characterization and structure of a new zinc(II) complex containing the hexadentate N,N′,N,N′-bis[(2-hydroxy-3,5-di-tert-butylbenzyl) (2-pyridylmethyl)]-ethylenediamine ligand:: Generation of phenoxyl radical species
    dos Anjos, A
    Bortoluzzi, AJ
    Szpoganicz, B
    Caro, MSB
    Friedermann, GR
    Mangrich, AS
    Neves, A
    INORGANICA CHIMICA ACTA, 2005, 358 (11) : 3106 - 3114
12345