Reversible Lithium-Ion Insertion in Molybdenum Oxide Nanoparticles

被引：342

作者：

Lee, Se-Hee ^{[2
]}

Kim, Yong-Hyun ^{[1
]}

Deshpande, Rohit ^{[3
]}

Parilla, Philip A. ^{[1
]}

Whitney, Erin ^{[1
]}

Gillaspie, Dane T. ^{[1
]}

Jones, Kim M. ^{[1
]}

Mahan, A. Harv ^{[1
]}

Zhang, Shengbai ^{[1
,4
]}

Dillon, Anne C. ^{[1
]}

机构：

[1] Natl Renewable Energy Lab, Mat & Computat Sci Ctr, Golden, CO 80401 USA

[2] Univ Colorado, Dept Mech Engn, Boulder, CO 80309 USA

[3] Lam Res Corp, Fremont, CA 94536 USA

[4] Rensselaer Polytech Inst, Dept Phys Appl Phys & Astron, Troy, NY 12180 USA

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 19期

关键词：

D O I：

10.1002/adma.200800999

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Li-ion battery anodes fabricated from crystalline MoO3 nanoparticles display an anomalous reversible capacity of 630 mAhg(-1) when cycled at high rate. The nanoparticle anodes show no degradation in capacity for 150 cycles, where micron sized MoO3 particles are shown to fail after several cycles. Theoretical calculations elucidate the Li-ion intercalation mechanism and explain the reversible capacity.

引用

页码：3627 / +

页数：7

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