Zinc-based metal complexes as new photocatalysts in polymerization initiating systems

被引：73

作者：

Tehfe, Mohamad-Ali ^{[1
]}

Dumur, Frederic ^{[2
]}

Telitel, Sofia ^{[1
]}

Gigmes, Didier ^{[2
]}

Contal, Emmanuel ^{[2
]}

Bertin, Denis ^{[2
]}

Morlet-Savary, Fabrice ^{[1
]}

Graff, Bernadette ^{[1
]}

Fouassier, Jean-Pierre ^{[3
]}

Lalevee, Jacques ^{[1
]}

机构：

[1] ENSCMu UHA, LRC CNRS 7228, IS2M, F-68057 Mulhouse, France

[2] Aix Marseille Univ, CNRS, Inst Chim Radicalaire, Equipe CROPS,UMR 7273,Fac Sci St Jerome, F-13397 Marseille 20, France

[3] UHA ENSCMu, F-68093 Mulhouse, France

来源：

EUROPEAN POLYMER JOURNAL | 2013年 / 49卷 / 05期

关键词：

Photocatalysts; Zinc complex (ZnC); Silane; Divinyl ether; Free radical polymerization; Cationic photopolymerization (ROP); SILYL RADICAL CHEMISTRY; CATIONIC PHOTOPOLYMERIZATION; VISIBLE-LIGHT; PHOTOINITIATORS; PHOTOLYSIS; CATALYSIS; ELECTRON; SILANE;

D O I：

10.1016/j.eurpolymj.2013.01.023

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Zinc-based metal complexes (ZnC) are proposed as original photoinitiators in multi-component systems for the formation of free radicals under visible light irradiation. The ZnC/iodonium salt/additive three-component systems (where the additive can be a silane or a divinyl ether) present an excellent ability to promote either the free radical polymerization of an acrylate, the cationic polymerization of a divinyl ether and the polymerization of acrylate/vinyl ether blends under very soft irradiations (e.g. halogen lamp irradiation) or laser diodes (457 or 532 nm) exposure. The mechanisms are investigated by photolysis, luminescence and ESR experiments. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：1040 / 1049

页数：10

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