Densimetric and ultrasonic characterization of urea and its derivatives in water

被引：32
|
作者：
Krakowiak, Joanna [1 ]
Wawer, Jaroslaw [1 ]
Panuszko, Aneta [1 ]
机构：
[1] Gdansk Univ Technol, Fac Chem, PL-80233 Gdansk, Poland
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2013年 / 58卷
关键词：
Density; Speed of sound; Apparent molar volume; Apparent molar isentropic compression; Urea; Hydration; PARTIAL MOLAR VOLUMES; METHYL-SUBSTITUTED UREAS; AQUEOUS-SOLUTIONS; MOLECULAR-DYNAMICS; AB-INITIO; APPARENT; COMPRESSIBILITIES; TETRAMETHYLUREA; PERCHLORATES; TEMPERATURE;
D O I：
10.1016/j.jct.2012.11.007
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The densities at T = (288.15, 293.15, 298.15, 303.15, and 308.15) K and sound velocities at T = 298.15 K have been measured for aqueous solutions of urea, N-methylurea, N,N'-dimethylurea, N,N,N'N'-tetramethylurea, N-ethylurea, N,N'-diethylurea, N-butylurea. From these data the apparent molar volumes, V-Phi the apparent molar isentropic compressions, K-S,K-Phi, and the Passynski solvation numbers of solutes have been determined. The concentration dependencies of the calculated quantities and their limiting values are discussed in terms of solute-solvent and solute-solute interactions. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：211 / 220
页数：10
相关论文
共 50 条
  • [21] Production and characterization of monoclonal antibodies against urea derivatives
    Rohde, M
    Schenk, JA
    Heymann, S
    Behrsing, O
    Scharte, G
    Kempter, G
    Woller, J
    Höhne, WE
    Warsinke, A
    Micheel, B
    APPLIED BIOCHEMISTRY AND BIOTECHNOLOGY, 1998, 75 (01) : 129 - 137
  • [22] Novel Phosphoranes Containing Urea Derivatives: Synthesis and Characterization
    Afshar, Davood Aghaei
    Islami, Mohammad Reza
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (09) : 2238 - 2246
  • [23] Production and characterization of monoclonal antibodies against urea derivatives
    Manuela Rohde
    Jörg A. Schenk
    Stephan Heymann
    Olaf Behrsing
    Gudrun Scharte
    Gerhard Kempter
    Jochen Woller
    Wolfgang E. Höhne
    Axel Warsinke
    Burkhard Micheel
    Applied Biochemistry and Biotechnology, 1998, 75 : 129 - 137
  • [24] Ultrasonic and Densimetric Characterization of the Association of Cyclic AMP with the cAMP-Binding Domain of the Exchange Protein EPAC1
    Son, Ikbae
    Selvaratnam, Rajeevan
    Dubins, David N.
    Melacini, Giuseppe
    Chalikian, Tigran V.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2013, 117 (37): : 10779 - 10784
  • [25] Water confined in reverse micelles: Acoustic and densimetric studies
    Amararene, A
    Gindre, M
    LeHuerou, JY
    Nicot, C
    Urbach, W
    Waks, M
    JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (50): : 10751 - 10756
  • [26] Studies on Stability and Moisture Retention of Urea and Its Derivatives
    Lv Yingfeng
    Lv Wanqi
    Zhou Jingmin
    China Detergent & Cosmetics, 2023, 8 (03) : 21 - 26
  • [27] SOME COMPLEXES OF DIHYDROXYURANYL WITH UREA AND ITS ALKYL DERIVATIVES
    DEMBINSKI, W
    DEPTULA, A
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1967, 29 (03): : 799 - +
  • [28] Hydration of urea and its derivatives - Volumetric and compressibility studies
    Krakowiak, Joanna
    Wawer, Jaroslaw
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2014, 79 : 109 - 117
  • [29] Urea and thiourea complexes with trifluoromethanesulfonic acid and its derivatives
    L. L. Tolstikova
    I. V. Sterkhova
    B. A. Shainyan
    Russian Journal of Organic Chemistry, 2014, 50 : 1247 - 1251
  • [30] Proton migration in molecular complexes of urea and its derivatives
    Jones, Andrew O. F.
    Thomas, L. H.
    McIntyre, G. J.
    Wilson, C. C.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C666 - C667
12345