Recent advances of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in photocatalytic transformations

被引：525

作者：

Shang, Tian-Yi ^{[1
]}

Lu, Ling-Hui ^{[2
]}

Cao, Zhong ^{[3
]}

Liu, Yan ^{[1
,4
]}

He, Wei-Min ^{[2
]}

Yu, Bing ^{[5
]}

机构：

[1] Xinyang Agr & Forestry Univ, Coll Biol & Pharmaceut Engn, Xinyang 464000, Peoples R China

[2] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China

[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Wanjiali Rd 960, Changsha 410114, Hunan, Peoples R China

[4] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Taoyuan Rd 9, Xiangtan 411201, Peoples R China

[5] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 38期

基金：

中国国家自然科学基金;

关键词：

VISIBLE-LIGHT PHOTOCATALYSIS; ALPHA-AMINO-ACIDS; C-H ALKYLATION; PHOTOREDOX CATALYSIS; CARBOXYLIC-ACIDS; ORGANIC-DYES; ALLYLIC ALCOHOLS; HETEROGENEOUS CATALYST; 1,2-ARYL MIGRATION; RADICAL REACTIONS;

D O I：

10.1039/c9cc01047e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron acceptor. It has emerged as a powerful organophotocatalyst since 2016. Excellent redox window, good chemical stability and broad applicability make 4CzIPN an attractive metal-free photocatalyst. In this review, the recent advances of the application of 4CzIPN as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized.

引用

页码：5408 / 5419

页数：12

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