Reaction of benzyl phenyl ketazine with PCl3: synthesis of substituted 1,2,3-diazaphosphole and its reactions with strong nucleophiles and bases

被引：1

作者：

Sushev, V. V. ^{[1
]}

Zolotareva, N., V ^{[1
]}

Grishin, M. D. ^{[1
]}

Panova, Yu S. ^{[1
]}

Khristolyubova, A., V ^{[1
]}

Baranov, E., V ^{[1
]}

Fukin, G. K. ^{[1
]}

Kornev, A. N. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, 49 Ul Tropinina, Nizhnii Novgorod 603137, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 10期

基金：

俄罗斯科学基金会;

关键词：

azines; diazadiphosphapentalenes; diazaphospholes; organolithium reagents; cyclic voltammetry; 3A,6A-DIAZA-1,4-DIPHOSPHAPENTALENE; PHOSPHORUS; COORDINATION; FEATURES;

D O I：

10.1007/s11172-022-3655-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of benzyl phenyl ketazine with PCl3 in tetrahydrofuran affords 2-(1,2-diphenylvinyl)-4,5-diphenyl-2H-[1,2,3]diazaphosphole (1). An unusual 1,3-addition of methyllithium at the nitrogen (N-Li) and phosphorus (P-Me) atoms of diazaphosphole was discovered. The reduction peak potentials of diazaphosphole (1) and the starting ketazine were measured by cyclic voltammetry.

引用

页码：2272 / 2279

页数：8

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