Electroactive Tetrathiafulvalenyl-1,2,3-triazoles by Click Chemistry: Cu- versus Ru-Catalyzed Azide-Alkyne Cycloaddition Isomers

被引：12
|
作者：
Biet, Thomas [1 ]
Cauchy, Thomas [1 ]
Avarvari, Narcis [1 ]
机构：
[1] Univ Angers, CNRS UMR 6200, Lab MOLTECH Anjou, LUNAM Univ, F-49045 Angers, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 50期
关键词：
click chemistry; coordination chemistry; crystal structures; nitrogen heterocycles; tetrathiafulvalene; TRANSITION-METAL-COMPLEXES; RADICAL-CATION; TERMINAL ALKYNES; CHARGE-TRANSFER; TETRATHIAFULVALENE; LIGANDS; 1,2,3-TRIAZOLES;
D O I：
10.1002/chem.201201905
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two series of 4- and 5-tetrathiafulvalenyl-1,2,3-triazoles, as multifunctional ligands and precursors for molecular materials, have been synthesized by copper- or ruthenium-based click chemistry. The solid-state structures of three ligands and two CuII complexes were determined. Large differences in the electron-donating properties between the 1,4- and 1,5-isomers were evidenced by cyclic voltammetry. Theoretical calculations support this observation and allow the assignment of the electronic transitions observed in UV/Vis spectra of the ligands.
引用
收藏
页码：16097 / 16103
页数：7
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