catena-Poly[[[triaquacadmium(II)]-μ-3-carboxylatophenoxyacetato-κ3O3,O3′:O"] sesquihydrate]

被引：1
|
作者：
Gao, S
Ng, SW [1 ]
机构：
[1] Heilongjiang Univ, Coll Chem & Mat Sci, Harbin 150080, Peoples R China
[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S160053680503850X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The dicarboxylate ligand in the title compound, [Cd(C9H6O5)(H2O) (3)]center dot 1.5H(2)O, bridges triaquacadmium groups into a linear chain; the carboxylate arm that is directly connected to the aromatic ring behaves as a chelate, whereas the carboxylate arm of the oxyacetate portion binds in a monodentate mode. The octahedral environment of cadmium is distorted towards a pentagonal bipyramid, owing to a long Cd center dot center dot center dot O interaction of 2.721 (2) angstrom.
引用
收藏
页码：M179 / M180
页数：2
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