Structure of Mn(II), Co(II), Ni(II), and Cu(II) complexes with triformylmethane

被引：1

作者：

Tretyakov, E. V. ^{[1
]}

Tolstikov, S. E. ^{[1
]}

Romanenko, G. V. ^{[1
]}

Bogomyakov, A. S. ^{[1
]}

Sagdeev, R. Z. ^{[1
,2
]}

Novotortsev, V. M. ^{[2
]}

Ovcharenko, V. I. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Siberian Div, Int Tomog Ctr, Novosibirsk, Russia

[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 117901, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2013年 / 54卷 / 01期

关键词：

manganese(II) complexes; cobalt(II) complexes; nickel(II) complexes; copper(II) complexes; 1,3-dicarbonyl compounds; X-ray diffraction analysis; METAL-COMPLEXES; CU-II; NITROXIDES;

D O I：

10.1134/S0022476613010149

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Previously unknown [ML2(H2O) (n) ] bischelates, where M is Mn(II), Co(II), Ni(II), or Cu(II) and L is deprotonated triformylmethane, are studied by X-ray diffraction analysis. It is revealed that in the crystals of all compounds there are multiple hydrogen bonds linking bischelate molecules into polymer layers or a single framework. The character of the temperature dependence of the effective magnetic moment [ML2(H2O) (n) ] indicates the existences of weak intracrystalline exchange interactions between the unpaired electrons of the paramagnetic centers.

引用

页码：104 / 109

页数：6

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