Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance

被引：44

作者：

Wang, Ya-Nong ^{[1
]}

Guo, Xu-Qing ^{[1
]}

Zhu, Xiao-Han ^{[1
]}

Zhong, Rui ^{[1
]}

Cai, Li-Hua ^{[1
]}

Hou, Xiu-Feng ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 84期

基金：

美国国家科学基金会;

关键词：

CROSS-COUPLING REACTIONS; C-H ACTIVATION; ARYL HALIDES; MECHANISM; CYCLOPALLADATION; TEMPERATURE; DERIVATIVES; COMPLEXES; KINETICS; MILD;

D O I：

10.1039/c2cc34949c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient arylation of electron-poor arenes has been developed without the addition of external ligands or in the presence of a catalytic monoprotected amino acid which assisted the reaction to proceed under mild conditions. The meta-selectivity was observed under both conditions.

引用

页码：10437 / 10439

页数：3

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