Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance

被引：44
|
作者：
Wang, Ya-Nong [1 ]
Guo, Xu-Qing [1 ]
Zhu, Xiao-Han [1 ]
Zhong, Rui [1 ]
Cai, Li-Hua [1 ]
Hou, Xiu-Feng [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 84期
基金：
美国国家科学基金会;
关键词：
CROSS-COUPLING REACTIONS; C-H ACTIVATION; ARYL HALIDES; MECHANISM; CYCLOPALLADATION; TEMPERATURE; DERIVATIVES; COMPLEXES; KINETICS; MILD;
D O I：
10.1039/c2cc34949c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient arylation of electron-poor arenes has been developed without the addition of external ligands or in the presence of a catalytic monoprotected amino acid which assisted the reaction to proceed under mild conditions. The meta-selectivity was observed under both conditions.
引用
收藏
页码：10437 / 10439
页数：3
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