Formal synthesis of FPA, a kainoid amino acid, via ketyl radical cyclization

被引：0

作者：

Kamabe, M ^{[1
]}

Miyazaki, T ^{[1
]}

Hashimoto, K ^{[1
]}

Shirahama, H ^{[1
]}

机构：

[1] Kwansei Gakuin Univ, Sch Sci, Nishinomiya, Hyogo 6628501, Japan

来源：

HETEROCYCLES | 2002年 / 56卷 / 1-2期

关键词：

samarium iodide; proton donor; stereochemistry; acromelic acid;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The formal synthesis of FPA, a kainoid amino acid, was performed through the SmI2 induced ketyl radical cyclization as the key step. The stereoselectivity was inverted in the presence or absence of the proton source.

引用

页码：105 / 111

页数：7

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