Catalytic Activity of Metal Nanoparticles Supported on Nitrogen-Doped Carbon Spheres

被引:32
|
作者
Deshmukh, Amit A. [1 ,2 ,3 ]
Islam, Rafique Ul [1 ,2 ]
Witcomb, Michael J. [3 ,4 ]
van Otterlo, Willem A. L. [1 ,2 ]
Coville, Neil J. [1 ,2 ,3 ]
机构
[1] Univ Witwatersrand, Inst Mol Sci, ZA-2050 Johannesburg, South Africa
[2] Univ Witwatersrand, Sch Chem, ZA-2050 Johannesburg, South Africa
[3] Univ Witwatersrand, DST NRF Ctr Excellence Strong Mat, ZA-2050 Johannesburg, South Africa
[4] Univ Witwatersrand, Microscopy & Microanal Unit, ZA-2050 Johannesburg, South Africa
关键词
C-C coupling; heterogeneous catalysis; hydrogenation; oxidation; supported catalysts; HECK REACTIONS; COUPLING REACTIONS; PALLADIUM NANOPARTICLES; FINE CHEMICALS; C-C; HYDROGENATION; SUZUKI; EFFICIENT; STABILITY; NANOTUBES;
D O I
10.1002/cctc.200900224
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sphere of influence: Various transition metal (Ru, Pd and V) particles supported on nitrogen-doped carbon nanospheres have been synthesized and their catalytic activity studied for the chemoselective hydrogenation of diketones, the oxidation of styrene, and C-C bond formation (Heck and Suzuki) reactions. The catalysts show very high activity, selectivity, and recyclability in these reactions. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:51 / 54
页数:4
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