Tetracyanoanthraquinodimethanes Having Biaryl Substituents: Synthesis, Crystal Structures, and Physical Properties

被引：12

作者：

Chiba, Hiroshi ^{[1
]}

Nishida, Jun-ichi ^{[1
]}

Yamashita, Yoshiro ^{[1
]}

机构：

[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMISTRY LETTERS | 2012年 / 41卷 / 05期

关键词：

CHARGE-TRANSFER COMPLEXES; ELECTRON-DONOR; ACCEPTOR; 11,11,12,12-TETRACYANO-9,10-ANTHRAQUINODIMETHANE; TCAQ; ARRAYS; DIMERS;

D O I：

10.1246/cl.2012.482

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

11,11,12,12-Tetracyano-9,10-anthraquinodimethane (TCNAQ) derivatives having four types of aryl substituents, phenyl, biphenyl-4-yl, thien-2-yl, and 2,2'-bithiophen-5-yl groups at their 2-position, were synthesized and characterized. Their crystal structures were determined by single-crystal X-ray structure analysis, revealing that the TCNAQ moiety and electron-donating substituents form donor acceptor-segregated columnar structures. The combination of nonplanar electron acceptor TCNAQ and planar donor units provides a good way to afford segregated columnar structures.

引用

页码：482 / 484

页数：3

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