Synthesis, crystal structure and magnetic properties of novel copper compound Cu(phen)(m-CBA)2

被引：3

作者：

Zhou Jian-liang ^{[1
]}

Huo Yan ^{[1
]}

Wang Min-min ^{[1
]}

Wang Yuan-yuan ^{[1
]}

Gu Ying-ying ^{[1
]}

Yi Xiao-yi ^{[1
]}

Zhang Shou-chun ^{[1
]}

机构：

[1] Cent S Univ, Sch Chem & Chem Engn, Key Lab Resources Chem Nonferrous Met, Changsha 410083, Hunan, Peoples R China

来源：

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA | 2011年 / 21卷 / 12期

基金：

中国国家自然科学基金;

关键词：

copper (II) compound; conventional synthesis; crystal structure; magnetic properties; ELECTROCHEMICAL PROPERTIES; HYDROTHERMAL SYNTHESIS; FRAMEWORK; NBO;

D O I：

10.1016/S1003-6326(11)61107-2

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

A novel compound Cu(phen)(m-CBA)(2) was synthesized with m-chlorobenzoic acid(m-CBA), 1,10-phenanthroline(phen) and Cu(OAc)(2)center dot H2O. It was characterized by IR, UV, elemental analyses and X-ray crystallography. It crystallizes in the monoclinic crystal system with C2/c space group, a=2.9699(4) nm, b=1.15452(2) nm, c=1.5335(2) nm, beta=111.118(2)degrees, V=4.905 1(1) nm(3), Z=8, F(000)=2 328, R-1=0.072 8, wR(2)=0.223 4 [I>2 sigma(I)]. Structure analysis shows that the copper center coordinates with two nitrogen atoms from one 1,10-phenanthroline molecule, two oxygen atoms from two m-chlorobenzoic acid molecules, giving a distorted squared planar coordination geometry. This novel compound shows paramagnetic interactions between copper centers.

引用

页码：2660 / 2664

页数：5

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