Methyl 2-[(methylsulfonyl)(propyl)amino]benzoate

被引:1
|
作者
Shafiq, Muhammad [2 ]
Tahir, M. Nawaz [1 ]
Khan, Islam Ullah [2 ]
Arshad, Muhammad Nadeem [2 ]
Haider, Zeeshan [2 ]
机构
[1] Univ Sargodha, Dept Phys, Sargodha, Pakistan
[2] Govt Coll Univ, Dept Chem, Lahore, Pakistan
关键词
D O I
10.1107/S1600536809054920
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, C(12)H(17)NO(4)S, contains two molecules, both of which show disorder of the two terminal C atoms of the propyl chain over two sets of sites with an occupancy ratio of 0.581 (6):0.419 (6). Intramolecular C-H center dot center dot center dot O interactions help to establish the molecular conformations: in one molecule, the dihedral angle between the methyl ester group and the benzene ring is 41.0 (2)degrees, whereas in the other molecule it is 36.12 (17)degrees. In the crystal, molecules are linked by intermolecular C-H center dot center dot center dot O and CH center dot center dot center dot pi interactions.
引用
收藏
页码:O248 / U3245
页数:14
相关论文
共 50 条
  • [41] MODIFIED SYNTHESES OF 2-(METHYLTHIO)-10-(2-(1-METHYL-2-PIPERIDINYL)ETHYL)PHENOTHIAZINE (THIORIDAZINE) AND 1-(3-(2-(METHYLSULFONYL)-10-PHENOTHIAZINYL)PROPYL)-PIPERIDINE-4-CARBOXAMIDE (METOPIMAZINE)
    SINDELAR, K
    HOLUBEK, J
    KORUNA, I
    HRUBANTOVA, M
    PROTIVA, M
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1990, 55 (06) : 1586 - 1601
  • [42] ON REACTION OF 2-(METHYLSULFONYL)QUINOLINE WITH NUCLEOPHILES
    HAYASHI, E
    SAITO, T
    YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1969, 89 (01): : 74 - +
  • [43] Methyl 2-[(1-oxo-1H-isochromen-3-yl)-methyl]benzoate
    Akkurt, Mehmet
    Yildirim, Sema Oeztuerk
    Bogdanov, Milen G.
    Mitrev, Yavor N.
    Heinemann, Frank W.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2824 - U1954
  • [44] Methyl 2-((succinimidooxy)carbonyl)benzoate (MSB):: A new, efficient reagent for N-phthaloylation of amino acid and peptide derivatives
    Casimir, JR
    Guichard, G
    Briand, JP
    JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (11): : 3764 - 3768
  • [45] Cyclization of phenacyl 2-{[2,2-di(ethoxycarbonyl)vinyl]amino}benzoate
    Hradil, P
    Kvapil, L
    Hlavac, J
    Lemr, K
    Sevcik, J
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1998, 63 (04) : 520 - 524
  • [46] Convenient synthesis of 2-(methylsulfonyl)pyrimidine derivatives
    Huang, Tong-Hui
    Zhou, Shan-Shan
    Wu, Xin
    An, Lin
    Yin, Xiao-Xing
    SYNTHETIC COMMUNICATIONS, 2018, 48 (06) : 714 - 720
  • [47] Methyl 3-amino-4-butanamido-5-methyl-benzoate
    Li, Xiang
    Yuan, Lian-shan
    Wang, Dan
    Yao, Cheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1063 - U2053
  • [48] 2-{[(Pyridin-2-yl)amino]methyl}phenol
    Gao, Shan
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02473 - +
  • [49] 2-{[(Pyrazin-2-yl)amino]methyl}phenol
    Gao, Shan
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02472 - +
  • [50] Synthesis,Crystal Structure and Neuroprotection of Methyl 2-((4-(2-(2-Methylphenoxy)acetyl)-piperazin-1-yl)-methyl)benzoate
    仲琰
    王垚
    王晶
    许逸
    李萍
    吴斌
    结构化学, 2014, 33 (07) : 1096 - 1101