1-(2-Hydroxy-3,4-dimethoxyphenyl)-2-(4-methoxyphenyl)ethanone

被引:3
|
作者
Xiao, Zhu-Ping [1 ]
Xiao, He-Ying [1 ]
机构
[1] Jishou Univ, Coll Chem & Chem Engn, Jishou 416000, Peoples R China
关键词
D O I
10.1107/S1600536808036258
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C(17)H(18)O(5), the pyrogallol group is almost coplanar with the mean plane of the attached carbonyl group [dihedral angle of 1.95 (13)degrees] and makes a dihedral angle of 56.01 (10)degrees with the other benzene ring. Of the three methoxy groups, only one is significantly twisted relative to its attached benzene ring [C-O-C-C torsion angles of 4.0 (5), 3.9 (6) and -106.3 (4)degrees]. Intramolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds help to establish the conformation, and the packing is consolidated by C-H center dot center dot center dot O interactions and pi-pi stacking interactions [centroid-centroid separation = 3.735 (2) angstrom].
引用
收藏
页码:O2324 / U2191
页数:9
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