Structural differences between Sr-2(VO)(AsO4)(2) and Ba-2(VO)(PO4)(2)

被引：0
|
作者：
Wadewitz, C [1 ]
MullerBuschbaum, H [1 ]
机构：
[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 09期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new alkaline earth vanadyl compounds, Sr-2(VO)(AsO4)(2) (I) and Ba-2(VO)(PO4)(2) (II), have been prepared by solid state reactions in closed quartz tubes and characterized by single crystal X-ray diffraction methods. Crystal data: (I): monoclinic, C-2h(6) - I2/a, a = 6.873(2), b = 16.307(4), c = 7.196(2) Angstrom, beta = 115.67(2), Z = 4; (II): monoclinic, C-2(3) - I2/a, a = 9.471(2), b = 5.443(1), c = 15.972(4) Angstrom, beta = 101.651(2), Z = 4. (I) is isotypic to Sr-2(VO)V2O8 and Sr-2(VO)(PO4)(2). (II) shows significant differences to the strontium compounds as well as to Ba-2(VO)(VO4)(2). The differences of the crystal chemistry and the similarity of (II) to Ba-2(VO)(PO4)(2) . H2O are discussed.
引用
收藏
页码：1290 / 1294
页数：5
相关论文
共 50 条
  • [21] Topotactic insertion of lithium in the layered structure Li4VO(PO4)2:: The tunnel structure Li5VO(PO4)2
    Kishore, M. Satya
    Pralong, V.
    CaIgnaert, V.
    Malo, S.
    Hebert, S.
    Varadaraju, U. V.
    Raveau, B.
    JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (04) : 976 - 982
  • [22] On a vanadyl oxocuprate phosphate CaCu(VO)(PO4)2 containing Cu2+ at positions of VO2+ ions and a copper rich phase CaCu1.13(VO)0.87(PO4)2
    Meyer, S
    Müller-Buschbaum, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1998, 53 (5-6): : 521 - 526
  • [23] Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates:: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2"-terpyridine)(VO2)( PO4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]
    Finn, RC
    Zubieta, J
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06): : 856 - 861
  • [24] Antiferromagnetism of Zn2VO(PO4)2 and the dilution with Ti4+
    Yogi, A.
    Ahmed, N.
    Nath, R.
    Tsirlin, A. A.
    Kundu, S.
    Mahajan, A. V.
    Sichelschmidt, J.
    Roy, B.
    Furukawa, Y.
    PHYSICAL REVIEW B, 2015, 91 (02)
  • [25] SULFURAPATITES - PREPARATION AND CRYSTAL-STRUCTURE OF BA5S(ASO4)2SO4, SR5S(ASO4)2SO4 AND SR5S(PO4)2SO4
    SCHIFFFRANCOIS, A
    SCHAFER, H
    SAVELSBERG, G
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1979, 34 (05): : 764 - 765
  • [26] PHASE COMPOSITION AND STRUCTURAL DIAGRAMS OF MG3(VO4)2-SR3(VO4)2,MG3(VO4)2-BA3(VO4)2 SYSTEMS
    FOTIEV, AA
    ZHURAVLEV, VD
    MAKAROV, VA
    ZHURNAL NEORGANICHESKOI KHIMII, 1977, 22 (06): : 1700 - 1701
  • [27] SYNTHESIS AND CHARACTERIZATION OF BA2VO4 WITH THE BETA-CA2SIO4 STRUCTURE - COMPARISON WITH SR2VO4
    LIU, G
    GREEDAN, JE
    JOURNAL OF SOLID STATE CHEMISTRY, 1993, 103 (01) : 228 - 239
  • [28] Synthesis and properties of LiZr2(AsO4)3 and LiZr2(AsO4) x (PO4)3-x
    Pet'kov, V. I.
    Sukhanov, M. V.
    Shipilov, A. S.
    Kurazhkovskaya, V. S.
    Borovikova, E. Yu.
    Pinus, I. Yu.
    Yaroslavtsev, A. B.
    INORGANIC MATERIALS, 2014, 50 (03) : 263 - 272
  • [29] ORDER AND DISORDER OF VANADYL CHAINS - CRYSTAL-STRUCTURES OF VANADYL DIHYDROGEN ARSENATE (VO(H2ASO4)2) AND THE LITHIUM DERIVATIVE LI4VO(ASO4)2
    ARANDA, MAG
    ATTFIELD, JP
    BRUQUE, S
    MARTINEZLARA, M
    INORGANIC CHEMISTRY, 1992, 31 (06) : 1045 - 1049
  • [30] The first vanadium gallophosphates:: Hydrothermal synthesis and structure of Rb[(VO)(H2O)Ga(PO4)2] and Cs[(VO)(H2O)Ga(PO4)2]
    Hammond, RP
    Zubieta, JA
    JOURNAL OF SOLID STATE CHEMISTRY, 1999, 144 (02) : 442 - 448
12345