Liquid phase aerobic oxidation of benzyl alcohol by using manganese ferrite supported-manganese oxide nanocomposite catalyst

被引：37

作者：

Elmaci, Gokhan ^{[1
]}

Ozer, Demet ^{[2
]}

Zumreoglu-Karan, Birgul ^{[2
]}

机构：

[1] Adiyaman Univ, Dept Chem, TR-02040 Adiyaman, Turkey

[2] Hacettepe Univ, Dept Chem, TR-06800 Ankara, Turkey

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 89卷

关键词：

Benzyl alcohol; Alcohol oxidation; Heterogeneous catalysis; MnOx catalysts; Magnetic nanocatalysts; OCTAHEDRAL MOLECULAR-SIEVES; SELECTIVE OXIDATIONS; FE3O4; NANOPARTICLES; HYDROGEN-PEROXIDE; BIRNESSITE; MNO2; EFFICIENT; WATER;

D O I：

10.1016/j.catcom.2016.10.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study illustrates for the first time the performance of nano-manganese ferrite supported-manganese oxide catalyst in benzyl alcohol (BzOH) oxidation without employing any oxidizing agent other than the air present in the reactor. The magnetic catalyst displayed moderate activity but 100% selectivity in conversion to benzaldehyde (BzH) under mild conditions. Compared to the other heterogeneous MnOx-based systems, the catalyst deserves attention in that an enhancement of the activity can be achieved by tuning the core-shell composition which plays a synergistic role in the catalytic reaction. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：56 / 59

页数：4

共 50 条

[41] Liquid phase oxidation of cinnamyl alcohol to cinnamaldehyde using multiwall carbon nanotubes decorated with zinc-manganese oxide nanoparticles
Sadiq, Mohammad
Saeed, Khalid
Sadiq, Saima
Munir, Sundas
Khan, Mashooq
APPLIED CATALYSIS A-GENERAL, 2017, 539 : 97 - 103
[42] Highly active and selective thallium doped ceria supported gold catalyst for benzyl alcohol aerobic oxidation
Santra, Chiranjit
Bravo-Suarez, Juan
Tao, Franklin
Sreedhar, Bojja
Pandei, Jai
Chowdhury, Biswajit
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
[43] Vanadium phosphorus oxide catalyst promoted by cobalt doping for mild oxidation of benzyl alcohol to benzaldehyde in the liquid phase
Mandavi, Vahid
Hasheminasab, Hamid Reza
APPLIED CATALYSIS A-GENERAL, 2014, 482 : 189 - 197
[44] Catalytic influence of mesoporous SBA-16 supported manganese molybdate on liquid phase selective oxidation of salicyl alcohol
Manimaran, Shanmugam
Tschentscher, Roman
Pandurangan, Arumugam
RESEARCH ON CHEMICAL INTERMEDIATES, 2022, 48 (09) : 3721 - 3737
[45] Catalytic influence of mesoporous SBA-16 supported manganese molybdate on liquid phase selective oxidation of salicyl alcohol
Shanmugam Manimaran
Roman Tschentscher
Arumugam Pandurangan
Research on Chemical Intermediates, 2022, 48 : 3721 - 3737
[46] Liquid Phase, Aerobic Oxidation of Benzyl Alcohol over the Catalyst System (Pt/TiO2+H2O)
Kunene, Avela
van Heerden, Tracey
Gambu, Thobani G.
van Steen, Eric
CHEMCATCHEM, 2020, 12 (19) : 4760 - 4764
[47] Property of a highly active bimetallic catalyst based on a supported manganese oxide for the complete oxidation of toluene
Kim, Sang Chai
Park, Young-Kwon
Nah, Jae Woon
POWDER TECHNOLOGY, 2014, 266 : 292 - 298
[48] NANO-GOLD SUPPORTED NICKEL MANGANESE OXIDE: SYNTHESIS, CHARACTERISATION AND EVALUATION AS OXIDATION CATALYST
Siddiqui, M. Rafiq H.
Warad, I.
Adil, S. F.
Mahfouz, R. M.
Al-Arifi, Abdullah
OXIDATION COMMUNICATIONS, 2012, 35 (02): : 476 - 481
[49] Catalytic Performance of Graphite Oxide Supported Au Nanoparticles in Aerobic Oxidation of Benzyl Alcohol: Support Effect
Huo, Yu-jia
Yao, Fan-fan
Ma, Yun-sheng
CHINESE JOURNAL OF CHEMICAL PHYSICS, 2017, 30 (01) : 90 - 96
[50] Tailoring manganese oxide catalysts for the total oxidation of pollutants in gas and liquid phase
Arena, Francesco
Di Chio, Roberto
Palella, Alessandra
Spadaro, Lorenzo
Frusteri, Leone
Fazio, Barbara
Morandi, Sara
Martra, Gianmario
APPLIED CATALYSIS A-GENERAL, 2021, 610 (610)

← 1 2 3 4 5 →