Stable, crystalline boron complexes with mono-, di- and trianionic formazanate ligands

被引：32

作者：

Mondol, Ranajit ^{[1
]}

Snoeken, Daan A. ^{[1
]}

Chang, Mu-Chieh ^{[1
]}

Otten, Edwin ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst Chem, Nijenborgh 4, NL-9747 AG Groningen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 03期

关键词：

NUCLEAR-MAGNETIC-RESONANCE; CATION-PI INTERACTIONS; BETA-DIKETIMINATE; DIFLUORIDE COMPLEXES; REDUCTION; ELECTRON; SHIFTS; DYES;

D O I：

10.1039/c6cc08166e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Redox-active formazanate ligands are emerging as tunable electron-reservoirs in coordination chemistry. Here we show that boron diphenyl complexes with formazanate ligands, despite their (formal) negative charge, can be further reduced by up to two electrons. A combined crystallographic, spectroscopic and computational study establishes that formazanate ligands are stable in mono-, di- and trianionic form.

引用

页码：513 / 516

页数：4

共 50 条

[41] PREPARATION OF MONO- DI- AND TRIETHYNYLALKYL(ARYL)SILANES
NOVIKOVA, OA
KUZNETSO.VP
KORNEV, KA
JOURNAL OF GENERAL CHEMISTRY USSR, 1968, 38 (01): : 177 - &
[42] Modelling the Hydrolysis of Mixed Mono-, Di- and Trimethyltin(IV) Complexes in Aqueous Solutions
Rosalia Maria Cigala
Francesco Crea
Concetta De Stefano
Silvio Sammartano
Journal of Solution Chemistry, 2015, 44 : 1611 - 1625
[43] Preparation and properties of mono-, di-, and tricalcium phosphates
Larson, HWE
INDUSTRIAL AND ENGINEERING CHEMISTRY-ANALYTICAL EDITION, 1935, 7 : 0401 - 0406
[44] Mono-, Di-, and Trinitrosoarenes: Modifiers for Cyanoacrylate Adhesives
Klyuchnikov O.R.
Khramov N.A.
Klyuchnikov Y.O.
Polymer Science - Series D, 2024, 17 (02) : 365 - 368
[45] Structural and Magnetochemical Properties of Mono-, Di-, and Trinuclear Manganese(III) Dithiolate Complexes
Seela, J. L.
Knapp, M. J.
Kolack, K. S.
Chang, H.-R.
Inorganic Chemistry, 37 (03):
[46] Spray drying of the mixtures of mono-, di-, and oligosaccharides
Wrzosek, Katarzyna
Moravcik, Juraj
Antosova, Monika
Illeova, Viera
Polakovic, Milan
ACTA CHIMICA SLOVACA, 2013, 6 (02): : 177 - 181
[47] Stability and infrared spectra of mono-, di-, and trichloromethanol
Wallington, TJ
Schneider, WF
Barnes, I
Becker, KH
Sehested, J
Nielsen, OJ
CHEMICAL PHYSICS LETTERS, 2000, 322 (1-2) : 97 - 102
[48] SYNTHESIS OF MONO- DI- AND TRIPEPTIDYL AMIDES OF DIHYDROSPHINGOSINE
WEISS, B
STILLER, RL
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1968, 13 (03): : 450 - &
[49] Syntheses of Mono-, Di-, and Trifluorinated Styrenic Monomers
Walkowiak, Justyna
del Campo, Teresa Martinez
Ameduri, Bruno
Gouverneur, Veronique
SYNTHESIS-STUTTGART, 2010, (11): : 1883 - 1890
[50] Mono-, di-, and oligonuclear complexes of CuII ions and p-hydroquinone ligands:: Syntheses, electrochemical properties, and magnetic Behavior
Margraf, G
Kretz, T
de Biani, FF
Laschi, F
Losi, S
Zanello, P
Bats, JW
Wolf, B
Removic-Langer, K
Lang, M
Prokofiev, A
Assmus, W
Lerner, HW
Wagner, M
INORGANIC CHEMISTRY, 2006, 45 (03) : 1277 - 1288

← 1 2 3 4 5 →