Time as a Dimension in High-Throughput Homogeneous Catalysis

被引：19

作者：

Blacquiere, Johanna M. ^{[1
]}

Jurca, Titel ^{[1
]}

Weiss, Joseph ^{[1
]}

Fogg, Deryn E. ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 18期

基金：

加拿大创新基金会; 加拿大自然科学与工程研究理事会;

关键词：

high-throughput screening; homogeneous catalysis; kinetics; metathesis; quenching;

D O I：

10.1002/adsc.200800596

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

High-throughput screening offers major opportunities to accelerate the discovery and optimization of homogeneously catalyzed reactions. A general method for acquisition of reaction profiles through a high-throughput quenching (HTQ) approach is described, which gives a more accurate picture of catalyst performance, e.g., total productivity, induction periods, selectivity and lifetime, than the customary analysis at a fixed, arbitrary time.

引用

页码：2849 / 2855

页数：7

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