Time as a Dimension in High-Throughput Homogeneous Catalysis

被引：19
|
作者：
Blacquiere, Johanna M. [1 ]
Jurca, Titel [1 ]
Weiss, Joseph [1 ]
Fogg, Deryn E. [1 ]
机构：
[1] Univ Ottawa, Dept Chem, Ctr Catalysis Res & Innovat, Ottawa, ON K1N 6N5, Canada
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2008年 / 350卷 / 18期
基金：
加拿大创新基金会; 加拿大自然科学与工程研究理事会;
关键词：
high-throughput screening; homogeneous catalysis; kinetics; metathesis; quenching;
D O I：
10.1002/adsc.200800596
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
High-throughput screening offers major opportunities to accelerate the discovery and optimization of homogeneously catalyzed reactions. A general method for acquisition of reaction profiles through a high-throughput quenching (HTQ) approach is described, which gives a more accurate picture of catalyst performance, e.g., total productivity, induction periods, selectivity and lifetime, than the customary analysis at a fixed, arbitrary time.
引用
收藏
页码：2849 / 2855
页数：7
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