A new type of luminescent alkynyl Au4Cu2 cluster

被引：63
|
作者：
de la Riva, H
Nieuwhuyzen, M
Fierro, CM
Raithby, PR
Male, L
Lagunas, MC [1 ]
机构：
[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
INORGANIC CHEMISTRY | 2006年 / 45卷 / 04期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1021/ic051503e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Changes in the optical properties of an alkynyldigold(I) complex upon reaction with Cu(I) are associated with a complicated structural change to form an unusual Au4Cu2 cluster with metallophilic interactions as well as pi-alkyne coordination.
引用
收藏
页码：1418 / 1420
页数：3
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