Structural Insights of Humins/Epoxidized Linseed Oil/Hardener Terpolymerization

被引：9

作者：

Licsandru, Erol ^{[1
]}

Gaysinski, Marc ^{[1
]}

Mija, Alice ^{[1
]}

机构：

[1] Univ Cote dAzur, Inst Chim Nice, UMR CNRS 7272, F-06108 Nice 02, France

来源：

POLYMERS | 2020年 / 12卷 / 07期

关键词：

renewable resources; biorefinery by-products; humins; copolymerization; epoxidized vegetal oils; reaction mechanism; H-1; C-13; NMR; VEGETABLE-OILS; SOYBEAN OIL; HYDROTHERMAL CARBONIZATION; PLANT OILS; HUMINS; EPOXY; ACID; EPOXIDATION; FRUCTOSE; PRODUCT;

D O I：

10.3390/polym12071583

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Bio-based thermosetting resins were synthesized from a ternary composition: humins; epoxidized linseed oil (ELO); and an industrial hardener, Capcure3-800 (CAP). Humins are in a focused attention in the last years, as biorefinery by-product, therefore its valorization through materials design is very important. Here we present a structural study of terpolymerization of humins/ ELO/CAP. The reactivity of these systems was highlighted by in situ FT-IR and(1)H and(13)C NMR. The integration of humins in thermosetting resins gives alternatives to new feedstocks for future bio-based materials.

引用

页码：1 / 17

页数：17

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