A novel rhodamine phosphorus derivative as fluorescent and colorimetric sensor for highly selective detection of Fe3+ in solution

被引：1
|
作者：
Lu, Luyu [1 ]
Yang, Honggao [1 ,2 ]
Guo, Peng [2 ]
Xu, Lei [2 ]
Huang, Junhai [2 ]
Ma, Jie [1 ]
机构：
[1] Univ Shanghai Sci & Technol, Sch Mat & Chem, Shanghai 200093, Peoples R China
[2] Shanghai Pharmaceut Ind Res Inst, State Key Lab Innovat Drugs & Pharmaceut Technol, Shanghai 201203, Peoples R China
来源：
OPTICAL MATERIALS | 2022年 / 133卷
基金：
上海市自然科学基金;
关键词：
Fe3+; Rhodamine; Fluorescence; Colorimetry; Sensor; ROAP; AQUEOUS-SOLUTION; PROBE; CHEMOSENSOR; DISCRIMINATION; SENSITIVITY; PHOSPHATE; IRON(III); SURFACE; CU2+; IONS;
D O I：
10.1016/j.optmat.2022.112767
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Based on Rhodamine moiety, a novel phosphorus fluorescent sensor as 2-(6-(diethylamino)-2-((diphenylphos-phoryl) methyl)-3-oxo-3-3H-xanthen-9-yl) benzoic acid (ROAP) is firstly designed and synthesized for the detection of Fe3+ in solution. The recognition effect of ROAP sensor is investigated carefully in dimethyl sulfoxide-water (DMSO-H2O) (f(w) = 70%) dispersion system. Fe3+ ion can lead to the quenching fluorescence and fading color of ROAP sensor. The as-prepared ROAP sensor shows high sensibility, selectivity, and anti-interference for Fe3+ in the concentration range of 0-5 equivalents. The recognition mechanism of the sensor is attributed to the combination of Fe3+ ions with the ROAP sensor via O atoms of P = O and OH groups. The stoichiometric ratio of ROAP and Fe3+ complexation is 2:1. The probe also exhibits good reversibility, and high potential commercial applications in the future.
引用
收藏
页数：6
相关论文
共 50 条
  • [31] A highly selective colorimetric sensor to Fe3+ and Co2+ in aqueous solutions
    Wang, Haiping
    Li, Juan
    Yao, Denghui
    Gao, Qun
    Guo, Fengqi
    Xie, Puhui
    [J]. RESEARCH ON CHEMICAL INTERMEDIATES, 2013, 39 (06) : 2723 - 2734
  • [32] A highly selective and sensitive fluorescent chemosensor for Fe3+ in physiological aqueous solution
    Hua, J
    Wang, YG
    [J]. CHEMISTRY LETTERS, 2005, 34 (01) : 98 - 99
  • [33] A Colorimetric and Fluorescent Probe Based on Rhodamine B for Detection of Fe3+ and Cu2+ Ions
    Yan, Liqiang
    Xie, Ya
    Li, Jianping
    [J]. JOURNAL OF FLUORESCENCE, 2019, 29 (05) : 1221 - 1226
  • [34] A Colorimetric and Fluorescent Probe Based on Rhodamine B for Detection of Fe3+ and Cu2+ Ions
    Liqiang Yan
    Ya Xie
    Jianping Li
    [J]. Journal of Fluorescence, 2019, 29 : 1221 - 1226
  • [35] Novel triazine-based colorimetric and fluorescent sensor for highly selective detection of Al3+
    Celestina, J. Jone
    Alphonse, L.
    Tharmaraj, P.
    Sheela, C. D.
    [J]. JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES, 2019, 4 (02): : 237 - 244
  • [36] Synthesis of rhodamine-helicin fluorescent probe for colorimetric detection of Cu2+ and fluorescent recognition of Fe3+
    Sun J.
    Shao Y.
    Li P.
    Yang Y.
    Gao C.-Y.
    Liu J.
    [J]. Sensors International, 2024, 5
  • [37] A Rhodamine-Based Sensor for Chromogenic Detection of Cu2+ and Fluorescent Detection of Fe3+
    YU Xianglin
    QU Hao
    HU Qihui
    HOU Kun
    YAN Yushi
    WU Dan
    ZHANG Pian
    LI Junbo
    [J]. Wuhan University Journal of Natural Sciences, 2014, 19 (02) : 129 - 136
  • [38] A novel ratiometric fluorescent probe for detection of Fe3+ by rhodamine-quinoline conjugate
    Qin, Jing-can
    Yang, Zheng-yin
    Wang, Guan-qun
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2015, 310 : 122 - 127
  • [39] A Highly Selective “Turn-on” Fluorescent Probe for Detection of Fe3+ in Cells
    Xiaorui Cao
    Feifei Zhang
    Yinjuan Bai
    Xiaohu Ding
    Wei Sun
    [J]. Journal of Fluorescence, 2019, 29 : 425 - 434
  • [40] A Highly Selective "Turn-on" Fluorescent Probe for Detection of Fe3+ in Cells
    Cao, Xiaorui
    Zhang, Feifei
    Bai, Yinjuan
    Ding, Xiaohu
    Sun, Wei
    [J]. JOURNAL OF FLUORESCENCE, 2019, 29 (02) : 425 - 434
12345