Palladium nanoparticles stabilized by sterically hindered phosphonium salts as Suzuki cross-coupling catalysts

被引：16
|
作者：
Ermolaev, V. V. [1 ]
Arkhipova, D. M. [1 ]
Nigmatullina, L. Sh. [1 ]
Rizvanov, I. Kh. [1 ]
Milyukov, V. A. [1 ]
Sinyashin, O. G. [1 ]
机构：
[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 03期
关键词：
palladium nanoparticles; bromoarenes; catalysis; cross-coupling; arylboronic acids; IONIC LIQUIDS; PD NANOPARTICLES; EFFICIENT CATALYSTS; ARYL HALIDES; SOLVENTS;
D O I：
10.1007/s11172-013-0088-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Palladium nanoparticles with an average size of 2.5 +/- 0.5 nm formed from palladium acetate in the presence of tri-tert-butyl(decyl)phosphonium tetrafluoroborate without an additional reducing agent exhibit high activity as a catalyst for the Suzuki cross-coupling reaction involving bromo- and chloroarenes under mild conditions.
引用
收藏
页码：657 / 660
页数：4
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