Visible-light mediated heterogeneous C-H functionalization: oxidative multi-component reactions using a recyclable titanium dioxide (TiO2) catalyst

被引：111
|
作者：
Vila, Carlos [1 ]
Rueping, Magnus [1 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源：
GREEN CHEMISTRY | 2013年 / 15卷 / 08期
关键词：
SELECTIVE PHOTOCATALYTIC OXIDATION; AROMATIC ALCOHOLS; AEROBIC OXIDATION; RADICAL-ADDITION; TERTIARY-AMINES; ALDEHYDES; EFFICIENT; IMINES; BONDS;
D O I：
10.1039/c3gc40587g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Visible-light mediated heterogeneous C-H functionalization of tertiary amines provides access to a variety of alpha-amino amides. An oxidative, titanium dioxide catalyzed, Ugi-type, three-component reaction has been developed in which the catalyst can be recycled without loss of activity.
引用
收藏
页码：2056 / 2059
页数：4
相关论文
共 50 条
  • [21] Visible-Light-Induced C-H Functionalization and C-C/C-X Bond-Forming Oxidative Cross-Coupling Reactions
    Zhang, Heng
    Lei, Aiwen
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (07) : 1164 - 1177
  • [22] Blue light mediated C-H arylation of heteroarenes using TiO2 as an immobilized photocatalyst in a continuous-flow microreactor
    Fabry, David C.
    Ho, Yee Ann
    Zapf, Ralf
    Tremel, Wolfgang
    Panthoefer, Martin
    Rueping, Magnus
    Rehm, Thomas H.
    GREEN CHEMISTRY, 2017, 19 (08) : 1911 - 1918
  • [23] Enhancing Ru(II)-Catalysis with Visible-Light-Mediated Dye-Sensitized TiO2 Photocatalysis for Oxidative C-H Olefination of Arene Carboxylic Acids at Room Temperature
    Dana, Suman
    Dey, Purusattam
    Patil, Siddappa A.
    Baidya, Mahiuddin
    CHEMISTRY-AN ASIAN JOURNAL, 2020, 15 (05) : 564 - 567
  • [24] Synthesis of edge-site selectively deposited Au nanocrystals on TiO2 nanosheets: An efficient heterogeneous catalyst with enhanced visible-light photoactivity
    Anwer, Shoaib
    Bharath, G.
    Iqbal, Shahid
    Qian, Hongmei
    Masood, Tariq
    Liao, Kin
    Cantwell, Wesley J.
    Zhang, Jiatao
    Zheng, Lianxi
    ELECTROCHIMICA ACTA, 2018, 283 : 1095 - 1104
  • [25] Carbon-titanium dioxide heterogeneous (photo)catalysts (C-TiO2) for highly efficient visible light photocatalytic application
    Lim, Chaehun
    An, Ha -Rim
    Lee, Hyeryeon
    Lee, Raneun
    Choi, Yunju
    Park, Ji -In
    Yoon, Jeechan
    Lee, Hyun Uk
    Lee, Young-Seak
    COMPOSITES PART B-ENGINEERING, 2022, 241
  • [26] High yield and greener C-H difluoromethylation reactions using copper iodide nanoparticles/boron nitride nanosheets as a versatile and recyclable heterogeneous catalyst
    Veerabagu, Udayakumar
    Jaikumar, Gowsika
    Lu, Fushen
    Quero, Franck
    REACTION CHEMISTRY & ENGINEERING, 2021, 6 (10) : 1900 - 1910
  • [27] Visible-light-mediated decarboxylative alkylation of 2-pyridone derivatives via a C3-selective C-H functionalization
    Niwetmarin, Worawat
    Saruengkhanphasit, Rungroj
    Eurtivong, Chatchakorn
    Ruchirawat, Somsak
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (42) : 9231 - 9236
  • [28] Water-Mediated C-H Cyanation of Quinoxalin-2(1H)-ones and Quinoxalines Under Visible-Light Conditions
    Badhani, Gaurav
    Adimurthy, Subbarayappa
    CHEMISTRYSELECT, 2023, 8 (27):
  • [29] Direct functionalization of the C-H bond in (hetero)arenes: aerobic photoinduced oxidative coupling of azines with aromatic nucleophiles (SN H-reactions) in the presence of a CdS/TiO2 photocatalyst
    Utepova, I. A.
    Chupakhin, O. N.
    Trestsova, M. A.
    Musikhina, A. A.
    Kucheryavaya, D. A.
    Charushin, V. N.
    Rempel, A. A.
    Kozhevnikova, N. S.
    Valeeva, A. A.
    Mikhaleva, A. I.
    Trofimov, B. A.
    RUSSIAN CHEMICAL BULLETIN, 2016, 65 (02) : 445 - 450
  • [30] A Novel, Multi-component Method of Preparation of Quinolines Using Recyclable CeO2-TiO2 Nanocomposite Catalyst under Solvent-free Conditions
    Khan, Sibaditya
    Agasar, Mallikarjun
    Ghosh, Arnab
    Keri, Rangappa S.
    ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2019, 51 (02) : 153 - 160
12345