Ir-Catalyzed enantioselective group transfer reactions

被引：24

作者：

Schafer, Andrew G. ^{[1
]}

Blakey, Simon B. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 17期

基金：

美国国家科学基金会;

关键词：

ALKYL-ALPHA-DIAZOESTERS; C-H INSERTION; CO(II)-BASED METALLORADICAL CATALYSIS; CHIRAL IRIDIUM(III) COMPLEX; CARBENE INSERTION; ORGANIC-SYNTHESIS; PORPHYRIN LIGAND; CYCLOPROPANATION; CYCLOPROPENATION; CONSTRUCTION;

D O I：

10.1039/c5cs00354g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recently, several novel iridium complexes have been shown to catalyse group transfer reactions in a highly selective fashion. Rhodium complexes, and in particular dirhodium tetracarboxylate salts, have proven to be a remarkably useful class of catalysts for these reactions through several decades of development. Recent results suggest that iridium may offer opportunities to address challenges in this chemistry and provide complementary reactivity patterns. This tutorial review outlines the recent developments in Ir-catalyzed enantioselective group transfer chemistry with highlights on examples which display this unique reactivity.

引用

页码：5969 / 5980

页数：12

共 50 条

[31] Ir-catalyzed reductive amination and transfer hydrogenation of diketones: access to β- and γ-amino alcohols
Tong, Jinghui
Guo, Shilin
Zhu, Huajie
Ouyang, Lu
Liao, Jianhua
Li, Youchun
RSC ADVANCES, 2024, 14 (51) : 38105 - 38109
[32] Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition
Shibata, Takanori
Uchiyama, Toshifumi
Yoshinami, Yusuke
Takayasu, Satoshi
Tsuchikama, Kyoji
Endo, Kohei
CHEMICAL COMMUNICATIONS, 2012, 48 (09) : 1311 - 1313
[33] Ir-catalyzed regio- and enantioselective Friedel-Crafts-type allylic alkylation of indoles
Liu, Wen-Bo
He, Hu
Dai, Li-Xin
You, Shu-Li
ORGANIC LETTERS, 2008, 10 (09) : 1815 - 1818
[34] Synthesis of 2-D-L-tryptophan by sequential Ir-catalyzed reactions
Vallakati, Ravikrishna
Plotnikov, Abel T.
Altman, Ryan A.
TETRAHEDRON, 2019, 75 (15) : 2261 - 2264
[35] Tunable ferrocenyl diphosphine ligands for the Ir-catalyzed enantioselective hydrogenation of N-aryl imines
Blaser, HU
Buser, HP
Häusel, R
Jalett, HP
Spindler, F
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 621 (1-2) : 34 - 38
[36] Highly Enantioselective Ir-Catalyzed Hydrogenation of Pyrazolo[1,5-a]pyrimidine for the Synthesis of Zanubrutinib
Yuan, Haohuan
Yao, Wei
Zhang, Xiaomin
Wei, Zhao
Xi, Jiayue
Hao, Yuanyuan
Liu, Xian
Jiang, Ru
Nie, Huifang
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (03): : 1748 - 1752
[37] A new class of modular phosphinite-oxazoline ligands: Ir-catalyzed enantioselective hydrogenation of alkenes
Blankenstein, J
Pfaltz, A
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (23) : 4445 - +
[38] Enantioselective synthesis of cis-hexahydro-γ-carboline derivatives via Ir-catalyzed asymmetric hydrogenation
Zheng, Long-Sheng
Yin, Congcong
Wang, Fangyuan
Chen, Gen-Qiang
Zhang, Xumu
CHEMICAL COMMUNICATIONS, 2022, 58 (20) : 3286 - 3289
[39] Highly enantioselective synthesis of both enantiomers of tetrahydroquinoxaline derivatives via Ir-catalyzed asymmetric hydrogenation
Xu, Ana
Ren, Lanxing
Huang, Junrong
Zhu, Yuxiang
Wang, Gang
Li, Chaoyi
Sun, Yongqiang
Song, Lijuan
You, Hengzhi
Chen, Fen-Er
CHEMICAL SCIENCE, 2024, 15 (37) : 15243 - 15254
[40] Facile construction of functionalized periodic mesoporous organosilica for Ir-catalyzed enantioselective reduction of α-cyanoacetophenones and α-nitroacetophenones
Chen, Chen
Kong, Lingyu
Cheng, Tanyu
Jin, Ronghua
Liu, Guohua
CHEMICAL COMMUNICATIONS, 2014, 50 (74) : 10891 - 10893

← 1 2 3 4 5 →