A First-Principles DFT Study on the Active Sites of Pd-Cu-Clx/Al2O3 Catalyst for Low-Temperature CO Oxidation

被引：11
|
作者：
Shen, Changli [1 ]
Li, Huiying [1 ]
Yu, Jun [1 ]
Wu, Guisheng [1 ]
Mao, Dongsen [1 ]
Lu, Guanzhong [1 ,2 ]
机构：
[1] Shanghai Inst Technol, Res Inst Appl Catalysis, Shanghai 201418, Peoples R China
[2] E China Univ Sci & Technol, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China
来源：
CHEMCATCHEM | 2013年 / 5卷 / 10期
基金：
中国国家自然科学基金;
关键词：
copper; density functional calculations; oxidation; palladium; reaction mechanisms; SUPPORTED PDCL2-CUCL2 CATALYSTS; CARBON-MONOXIDE OXIDATION; WACKER-TYPE CATALYSTS; CU CATALYSTS; ALUMINA; PD; TRANSITION; MECHANISM; MOISTURE; METALS;
D O I：
10.1002/cctc.201300356
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A tandem cycle ride: The catalytic reaction mechanism of CO oxidation over Pd-Cu-Clx/γ-Al2O3 is proposed based on DFT studies. There are two catalytic cycles in the CO oxidation process, the palladium cycle(- (green)) and the copper cycle(- (red)). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：2813 / 2817
页数：5
相关论文
共 50 条
  • [1] Stability of Pd-Cu-Clx/Al2O3 catalyst for CO oxidation
    Wang, Li
    Lu, Xiaoqing
    Wang, Wei
    Zhan, Wangcheng
    Guo, Yanglong
    Guo, Yun
    CHINESE JOURNAL OF CATALYSIS, 2018, 39 (09) : 1560 - 1567
  • [2] Study on the catalytic reaction mechanism of low temperature oxidation of CO over Pd-Cu-Clx/Al2O3 catalyst
    Shen, Yuexin
    Lu, Guanzhong
    Guo, Yun
    Wang, Yanqin
    Guo, Yanglong
    Gong, Xueqing
    CATALYSIS TODAY, 2011, 175 (01) : 558 - 567
  • [3] The stability and deactivation of Pd-Cu-Clx/Al2O3 catalyst for low temperature CO oxidation: an effect of moisture
    Shen, Yuexin
    Guo, Yun
    Wang, Li
    Wang, Yanqin
    Guo, Yanglong
    Gong, Xueqing
    Lu, Guanzhong
    CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (07) : 1202 - 1207
  • [4] A synthesis of high-efficiency Pd-Cu-Clx/Al2O3 catalyst for low temperature CO oxidation
    Shen, Yuexin
    Lu, Guanzhong
    Guo, Yun
    Wang, Yanqin
    CHEMICAL COMMUNICATIONS, 2010, 46 (44) : 8433 - 8435
  • [5] Realization of a highly effective Pd-Cu-Clx/Al2O3 catalyst for low temperature CO oxidation by pre-synthesizing the active copper phase of Cu2Cl(OH)3
    Du, Xuexun
    Li, Hui-Ying
    Yu, Jun
    Xiao, Xiuzhen
    Shi, Zhangping
    Mao, Dongsen
    Lu, Guanzhong
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (08) : 3970 - 3979
  • [6] Identification of active sites in CO oxidation over a Pd/Al2O3 catalyst
    Murata, Kazumasa
    Eleeda, Eleen
    Ohyama, Junya
    Yamamoto, Yuta
    Arai, Shigeo
    Satsuma, Atsushi
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2019, 21 (33) : 18128 - 18137
  • [7] Design of a highly active Pt/Al2O3 catalyst for low-temperature CO oxidation
    An, Nihong
    Yuan, Xiaoling
    Pan, Bo
    Li, Qinglin
    Li, Suying
    Zhang, Wenxiang
    RSC ADVANCES, 2014, 4 (72) : 38250 - 38257
  • [8] Deactivation and stability of Au/Al2O3 catalyst for CO low-temperature oxidation
    Zou, XH
    Qi, SX
    Suo, ZH
    An, LD
    Li, F
    CHINESE JOURNAL OF CATALYSIS, 2006, 27 (02) : 161 - 165
  • [9] Activity and deactivation of Au/Al2O3 catalyst for low-temperature CO oxidation
    Zou, Xu-hua
    Qi, Shi-xue
    Suo, Zhang-huai
    An, Li-dun
    Li, Feng
    CATALYSIS COMMUNICATIONS, 2007, 8 (05) : 784 - 788
  • [10] Pd-Cu-Clx/Al2O3催化剂对CO氧化的稳定性（英文）
    王丽
    路小清
    王维
    詹望成
    郭杨龙
    郭耘
    Chinese Journal of Catalysis, 2018, (09) : 1560 - 1567
12345